H2 in neat (no solvent)
formation on passing CFCl3 and H2 (molar ratio 1:2) through a glass tube heated to red heat or inflammation of the mixture at the outlet of a capillary; luminescense is observed;;
参考文献
Ruff, O.; Keim, R.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1931 , vol. 201, p. 245 - 258
Ruff; Keim
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1931 , vol. 201, p. 250,252
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Plank
Ang.Ch.Beih., 1942 , vol. 44, p. 2
in neat (no solvent)
byproducts: CO; pyrolysis in a Al2O3-vessel above 400°C; mechanism discussed; above 650°C formation of CO by reaction with the vessel;; yields given, depending on temp.;;
参考文献
Trenwith, A. B.; Watson, R. H.
Journal of the Chemical Society, 1957 , p. 2368 - 2372