Aynsley, E. E.; Watson, R. H.
Journal of the Chemical Society, 1953 , p. 3016 - 3019
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Gmelin Handbook: C: MVol.D2, 4.3.2.5.6, page 371 - 372
in neat (no solvent) reaction at 500°C; mechanism discussed;;
参考文献
Aynsley, E. E.; Watson, R. H.
Journal of the Chemical Society, 1953 , p. 3016 - 3019
Full Text View citing articles Show Details
Gmelin Handbook: C: MVol.D2, 4.3.2.5.6, page 371 - 372
H2 in perdeuterocyclohexane byproducts: CF2H2; under N2; in a resealable NMR tube Zr complex was dissolved in cyclohexane-d12, the tube was freeze-pump-thaw degassed 3 times, CF2Cl2 was condensed at -196°C , H2 was added, upon thawing, a ppt. formed; not isolated, detected by NMR;
参考文献
Journal of the American Chemical Society, , vol. 123, # 44 p. 10973 - 10979
H2 in perdeuterocyclohexane byproducts: methane; under N2; in a resealable NMR tube Zr complex was dissolved in cyclohexane-d12, the tube was freeze-pump-thaw degassed 3 times, CF2Cl2 was condensed at -196°C , H2 was added, the mixt. was heated at 120°C for 11 d; not isolated, detected by NMR;
参考文献
Journal of the American Chemical Society, , vol. 123, # 44 p. 10973 - 10979