in neat (no solvent) passing CCl4 over calcinated Na3AlF6-pellets or over a mixture of Na3AlF6 and sand at 375-400°C;; yield depending on temp. and size of the pellets;;
in neat (no solvent) Kinetics; gas phase reaction; determination of kinetic by fluorination of CF2Cl2-C2F5Cl and CF2Cl2-1.2-C2F4Cl2-mixtures at 596-790K;; enthalpy of reaction;;
参考文献
J. Chem. Soc. Faraday Trans. I, , vol. 68, p. 1121 - 1130
Harris, G. S.
Journal of the Chemical Society, 1958 , p. 512 - 519
Full Text View citing articles Show Details
Gmelin Handbook: F: PerFHalOrg.3, 1.8, page 51 - 70
in neat (no solvent) byproducts: CO; pyrolysis in a Al2O3-vessel above 400°C; mechanism discussed; above 650°C formation of CO by reaction with the vessel;; yields given, depending on temp.;;
