hydrogenchloride in tetrahydrofuran mixing of CrPh2 with Li-salt in THF (molar ratio 1:1.5, -78°C, 1 h), rise of temp. to 25°C (over 1 h); gas liquid chromy. after quenching with 2 N HCl;
参考文献
Negishi, Ei-ichi; Akiyoshi, Kazunari; O'Connor, Brian; Takagi, Kentaro; Wu, Guangzhong
Journal of the American Chemical Society, 1989 , vol. 111, # 8 p. 3089 - 3091
hydrogenchloride in tetrahydrofuran mixing of MnPh2 with Li-salt in THF (molar ratio 1:2, -78°C, 1 h), rise of temp. to 25°C (over 1 h); gas liquid chromy. after quenching with 2 N HCl;
参考文献
Journal of the American Chemical Society, , vol. 111, # 8 p. 3089 - 3091
hydrogenchloride in tetrahydrofuran mixing of Hf-complex with Li-salt in THF (molar ratio 1:1.3, -78°C, 1 h), rise of temp. to 25°C (over 1 h); gas liquid chromy. after quenching with 2 N HCl;
参考文献
Journal of the American Chemical Society, , vol. 111, # 8 p. 3089 - 3091
hydrogenchloride in tetrahydrofuran mixing of Zr-complex with Li-salt in THF (molar ratio 1:1, -78°C, 1 h), rise of temp. to 25°C (over 1 h); gas liquid chromy. after quenching with 2 N HCl;
参考文献
Negishi, Ei-ichi; Akiyoshi, Kazunari; O'Connor, Brian; Takagi, Kentaro; Wu, Guangzhong
Journal of the American Chemical Society, 1989 , vol. 111, # 8 p. 3089 - 3091
CH2Cl2 in dichloromethane exposure of Cr-compound to NOPF6 in CH2Cl2; elem. anal.;
参考文献
Herring, F. Geoffrey; Legzdins, Peter; McNeil, W. Stephen; Shaw, Michael J.; Batchelor, Raymond J.; Einstein, Frederick W. B.
Journal of the American Chemical Society, 1991 , vol. 113, p. 7049 - 7050
hydrogenchloride in tetrahydrofuran mixing of VPh3 with Li-salt in THF (molar ratio 1:1.5, -78°C, 1 h), rise of temp. to 25°C (over 1 h); gas liquid chromy. after quenching with 2 N HCl;
参考文献
Journal of the American Chemical Society, , vol. 111, # 8 p. 3089 - 3091
HCl in toluene bubbling of HCl(g) to the Ru compd. in toluene at room temp. for 1 h; evapn. (vacuum), washing with hexane and recrystn. from toluene-hexane at -30°C; elem. anal.;
参考文献
Shapley, Patricia A.; Kim, Hoon sik; Wilson, Scott R.
Organometallics, 1988 , vol. 7, p. 928 - 933
