H2 in toluene Copper-complex is hydrogenated under 3 atm of H2 in toluene, the color of the soln. changes quickly from yellow to orange (under exclusion of air).; investigation by (1)H NMR;
H2 in toluene Copper-complex is hydrogenated under 3 atm of H2 in toluene, the color of the soln. changes quickly from yellow to orange (under exclusion of air).; investigation by (1)H NMR;
in 1,4-dioxane In inert atmosphere, refluxing of Ru-complex with HSiCl3 (3 h).; Evapn. of volatiles in vac., extg. (diethyl ether), cooling of pale yellow soln. (-40°C), mixt. is not sepd., IR.;
参考文献
Journal of the American Chemical Society, , vol. 112, # 7 p. 2673 - 2681
in benzene The mixt. of reagents in benzene was heated at 160-165°C for 3 weeks in a sealed tube;; not sepd., detected by NMR 13P spectra;;
参考文献
Beachley, O. T.; Kopasz, John P.; Zhang, Hongming; Hunter, William E.; Atwood, Jerry L.
Journal of Organometallic Chemistry, 1987 , vol. 325, p. 69 - 82
