sodium in diethyl ether T=50°C; 60 h; other dihalocyclopentenes; other temperatures, metals and solvents; influence of NaBr; scope and limitation of the reaction; Product distributionMechanism;
in diethyl ether mixt. of (CH3)3SiCH2MgCl and (CH3)3SiCl in ether; heating under evapn. of the ether during a longer period of time;;
参考文献
Sommer et al.
Journal of the American Chemical Society, 1947 , vol. 69, p. 980
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Sommer, L. H.; Mitch, F. A.; Godberg, G. M.
Journal of the American Chemical Society, 1949 , vol. 71, p. 2746 - 2750
sodium in toluene slow addn. of Na to a mixt. of (CH3)3SiCH2Cl, (CH3)3SiCl and toluene;;
参考文献
Gmelin Handbook: Si: MVol.C, 29, page 90 - 93
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Dow Corning Corp.
Patent: US2507513 , 1950 ;
C. I, 1951 , p. 119
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Dow Corning Corp.
Patent: US2511812 , 1950 ;
C. A., 1950 , p. 8362
