2,2,2-三氟乙醇合成路线 （共 1089 条）
反应条件
1: 2,2,2-trifluoroethanol With sodium t-butanolate in toluene
T=0 - 20°C; 0.25 h; Inert atmosphere;
2: (4-nitrophenyl)(phenyl)iodonium triflate in toluene
T=0 - 20°C; Inert atmosphere; Reagent/catalystSolventTimeTemperature; chemoselective reaction;
参考文献
Ghosh, Raju; Lindstedt, Erik; Jalalian, Nazli; Olofsson, Berit
ChemistryOpen, 2014 , vol. 3, # 2 p. 54 - 57
反应条件
copper(l) iodide; caesium carbonate; ethyl 2-oxo-cyclohexanecarboxylate
17 h; Neat (no solvent)Reflux;
参考文献
Vukga, Daniela; Legros, Juelien; Crousse, Benoit; Bonnet-Delpon, Daniele
European Journal of Organic Chemistry, 2009 , # 21 p. 3513 - 3518
参考文献
Canning, Peter S. J.; Maskill, Howard; McCrudden, Katharine; Sexton, Brian
Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 4 p. 789 - 800
反应条件
Ambient temperatureIrradiation;
参考文献
Canning, Peter S. J.; McCrudden, Katharine; Maskill, Howard; Sexton, Brian
Chemical Communications, 1998 , # 18 p. 1971 - 1972
反应条件
copper(l) iodide; caesium carbonate; ethyl 2-oxo-cyclohexanecarboxylate
17 h; Neat (no solvent)Reflux;
参考文献
Vukga, Daniela; Legros, Juelien; Crousse, Benoit; Bonnet-Delpon, Daniele
European Journal of Organic Chemistry, 2009 , # 21 p. 3513 - 3518
反应条件
copper(l) iodide; caesium carbonate; ethyl 2-oxo-cyclohexanecarboxylate
17 h; Neat (no solvent)Reflux;
参考文献
Vukga, Daniela; Legros, Juelien; Crousse, Benoit; Bonnet-Delpon, Daniele
European Journal of Organic Chemistry, 2009 , # 21 p. 3513 - 3518
反应条件
caesium carbonate
7 h; UV-irradiation;
参考文献
Dichiarante, Valentina; Salvaneschi, Andrea; Protti, Stefano; Dondi, Daniele; Fagnoni, Maurizio; Albini, Angelo
Journal of the American Chemical Society, 2007 , vol. 129, # 51 p. 15919 - 15926
反应条件
caesium carbonate
7 h; UV-irradiation;
参考文献
Dichiarante, Valentina; Salvaneschi, Andrea; Protti, Stefano; Dondi, Daniele; Fagnoni, Maurizio; Albini, Angelo
Journal of the American Chemical Society, 2007 , vol. 129, # 51 p. 15919 - 15926
反应条件
caesium carbonate
12 h; UV-irradiation;
参考文献
Dichiarante, Valentina; Salvaneschi, Andrea; Protti, Stefano; Dondi, Daniele; Fagnoni, Maurizio; Albini, Angelo
Journal of the American Chemical Society, 2007 , vol. 129, # 51 p. 15919 - 15926
反应条件
caesium carbonate
Irradiation;
参考文献
Protti, Stefano; Fagnoni, Maurizio; Mella, Mariella; Albini, Angelo
Journal of Organic Chemistry, 2004 , vol. 69, # 10 p. 3465 - 3473
