2,2,2-三氟乙醇合成路线 （共 1089 条）
反应条件
sodium carbonate in water
T=25°C; 24 h; other buffers; percent rearrangement in different solvents; Product distribution;
参考文献
Hanack, Michael; Collins, Clair J.; Stutz, H.; Benjamin, Ben M.
Journal of the American Chemical Society, 1981 , vol. 103, # 9 p. 2356 - 2360
反应条件
Ambient temperature;
参考文献
Hebel, David; Rozen, Shlomo
Journal of Organic Chemistry, 1991 , vol. 56, # 22 p. 6298 - 6301
反应条件
trifluoroacetic acid sodium salt
参考文献
Fujita, Morifumi; Ihara, Kenji; Kim, Wan Hyeok; Okuyama, Tadashi
Bulletin of the Chemical Society of Japan, 2003 , vol. 76, # 9 p. 1849 - 1855
反应条件
triethylamine in tetrahydrofuran
T=-20°C;
参考文献
Denney,D.B.; Denney,D.Z.; Hammond,P.J.
Journal of the American Chemical Society, 1981 , vol. 103, p. 1785
参考文献
Broxton, Trevor J.
Australian Journal of Chemistry, 1984 , vol. 37, # 1 p. 47 - 54
反应条件
in water
T=25°C; different solvent/reagent ratio; other solvent; Product distributionRate constant;
参考文献
Shiner, V. J.; Ensinger, Mark W.
Journal of the American Chemical Society, 1986 , vol. 108, # 4 p. 842 - 844
参考文献
Bogolubsky, Andrey V.; Ryabukhin, Sergey V.; Pipko, Sergey E.; Lukin, Oleg; Shivanyuk, Alexander; Mykytenko, Dmytro; Tolmachev, Andrey
Tetrahedron, 2011 , vol. 67, # 20 p. 3619 - 3623
参考文献
Oliverio; Sawicki
Journal of Organic Chemistry, 1955 , vol. 20, p. 363,364
反应条件
perchloric acid; sodium perchlorate in acetonitrile
T=25°C; Equilibrium constant;
参考文献
Richard, John P.; Jagannadham, Vandannapu; Amyes, Tina L.; Mishima, Masaaki; Tsuno, Yuho
Journal of the American Chemical Society, 1994 , vol. 116, # 15 p. 6706 - 6712
参考文献
Brown,H.C.; Wetzel,C.R.
Journal of Organic Chemistry, 1965 , vol. 30, p. 3724 - 3728
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Gmelin Handbook: F: PerFHalOrg.9, 7, page 50 - 101
