2,2,2-三氟乙醇合成路线 (共 1089 条)
反应条件
water T=41.6 - 41.9°C; solvolysis with or withont added electrolytes; Kinetics;
参考文献
Maskill, H.; Jencks, William P.
Journal of the American Chemical Society, 1987 , vol. 109, # 7 p. 2062 - 2070
参考文献
Bentley, T. William; Jones, Robert O; Kang, Dae Ho; Koo, Sun
Journal of Physical Organic Chemistry, 2009 , vol. 22, # 9 p. 799 - 806
反应条件
water; sodium acetate T=42°C; products from solvolysis, containing unbuffered or buffered sodium acetate; Product distribution;
参考文献
Maskill, H.; Jencks, William P.
Journal of the American Chemical Society, 1987 , vol. 109, # 7 p. 2062 - 2070
反应条件
water T=42°C; products from solvolysis in the presence of imidazole buffers; Product distribution;
参考文献
Maskill, H.; Jencks, William P.
Journal of the American Chemical Society, 1987 , vol. 109, # 7 p. 2062 - 2070
反应条件
also with NaOAc or imidazole in water T=42°C; MechanismProduct distributionRate constant;
参考文献
Maskill, H.
Journal of the Chemical Society, Chemical Communications, 1986 , p. 1433 - 1435
反应条件
sulfuric acid; hydroquinone in benzene Heating;
参考文献
KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY
Patent: US2005/85661 A1, 2005 ;
Location in patent: Page/Page column 5 ;
反应条件
2,6-di-tert-butyl-4-methyl-phenol; triethylamine
参考文献
Raihane; Ameduri
Journal of Fluorine Chemistry, 2006 , vol. 127, # 3 p. 391 - 399
反应条件
potassium 2,2,2-trifluoroethoxide T=30°C; μ = 0.05 M with potassium trifluoroacetate; Rate constant;
参考文献
Xu, Yiying; Dietze, Paul E.
Journal of the American Chemical Society, 1993 , vol. 115, # 23 p. 10722 - 10727
反应条件
in water T=80°C; 18 h;
参考文献
Hill, David R; Hsiao, Chi-Nung; Kurukulasuriya, Ravi; Wittenberger, Steven J
Organic letters, 2002 , vol. 4, # 1 p. 111 - 113
参考文献
Bailey, Anne E.; Hill, David R.; Hsiao, Chi-Nung W.; Kurukulasuriya, Ravi; Wittenberger, Steve; McDermott, Todd; McLaughlin, Maureen A.
Patent: US2002/19539 A1, 2002 ;
US 20020019539 A1