2,2,2-三氟乙醇合成路线 （共 1089 条）
反应条件
2,6-dimethylpyridine T=100°C; nucleophilic selectivity and stereoselectivity; MechanismProduct distribution;
参考文献
Sinnott, Michael L.; Jencks, William P.
Journal of the American Chemical Society, 1980 , vol. 102, # 6 p. 2026 - 2032
反应条件
hydrogen fluoride; boron trifluoride T=150°C; Etherification; 14 h;
参考文献
Petrov, Viacheslav A.; Davidson, Fred
Journal of Fluorine Chemistry, 1999 , vol. 95, # 1-2 p. 5 - 14
反应条件
T=55°C; Kinetics; Concentration;
参考文献
Park, Kyoung-Ho; Kevill, Dennis N.
Journal of Physical Organic Chemistry, 2012 , vol. 25, # 3 p. 267 - 270
反应条件
triethylamine in dichloromethane 2 h; 0 deg C to r.t.;
参考文献
Nakatani, Takuji; Hiratake, Jun; Yoshikawa, Kazuhiro; Nishioka, Takaaki; Oda, Jun'ichi
Bioscience, Biotechnology, and Biochemistry, 1992 , vol. 56, # 7 p. 1118 - 1123
反应条件
phosphate buffer; N-hexadecyl-N,N,N-trimethylammonium bromide; sodium bromide T=25°C; pH=11.60; Kinetics;
参考文献
Tee; Yazbeck
Canadian Journal of Chemistry, 2000 , vol. 78, # 8 p. 1100 - 1108
反应条件
in water T=50°C; Rate constant;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 72, # 5 p. 1043 - 1047
反应条件
in water T=50°C; Rate constant;
参考文献
Nakashima, Tohru; Fujiyama, Ryoji; Fujio, Mizue; Tsuno, Yuho
Bulletin of the Chemical Society of Japan, 1999 , vol. 72, # 5 p. 1043 - 1047
反应条件
2,6-dimethylpyridine T=90°C; Yield given. Yields of byproduct given;
参考文献
Dombrowski, Gary W.; Gassman, Paul G.; Kass, Steven R.
Tetrahedron Letters, 1997 , vol. 38, # 45 p. 7819 - 7822
反应条件
T=130°C; 340 h; Product distribution; Further Variations:reaction time;
参考文献
Fujita, Morifumi; Mishima, Eri; Okuyama, Tadashi
Journal of Physical Organic Chemistry, 2007 , vol. 20, # 4 p. 241 - 244
参考文献
Gmelin Handbook: B: B-Verb.10, 4.8.7.2, page 248 - 252
Full Text Show Details
Olah, G. A.; Kuhn, S. J.
Olah, G. A., Friedel-Crafts and Related Reactions, Bd. 3, Tl. 2, Interscience Publishers, New York - London - Sydney 1964, S. 1393/491
