2,2,2-三氟乙醇合成路线 （共 1089 条）
反应条件
4-(N,N-dimethlyamino)pyridine; dicyclohexyl-carbodiimide in dichloromethane T=0 - 20°C; Inert atmosphereSchlenk technique;
参考文献
He, Guangrui; Wan, Xiangjian; Li, Zhi; Zhang, Qian; Long, Guankui; Liu, Yongsheng; Hou, Yanhui; Zhang, Mingtao; Chen, Yongsheng
Journal of Materials Chemistry C, 2014 , vol. 2, # 7 p. 1337 - 1345
反应条件
2,3-dimethyl aniline in dichloromethane 2 h; Heating;
参考文献
Lei, Yi Xiong; Casarini, Daniele; Cerioni, Giovanni; Rappoport, Zvi
Journal of Organic Chemistry, 2003 , vol. 68, # 3 p. 947 - 959
→
2356-01-61,3,3,4,4,5,5,6,6-九氟-2-(2,2,2-三氟乙氧基)环己烯
反应条件
potassium hydroxide Ambient temperature;
参考文献
Clayton,A.B. et al.
Journal of the Chemical Society, 1965 , p. 7358 - 7367
反应条件
sodium carbonate T=80°C; 216 h; Further byproducts given;
参考文献
Collins, Clair J.; Hanack, Michael; Stutz, Herbert; Auchter, Gerhard; Schoberth, Winfried
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5260 - 5268
参考文献
Foehlisch, Baldur; Franz, Thilo; Kreiselmeier, Guenter
European Journal of Organic Chemistry, 2005 , # 21 p. 4687 - 4698
反应条件
palladium diacetate; potassium carbonate; 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in acetone T=50°C; 24.3333 h; Inert atmosphereGlovebox;
参考文献
Tschaen, Brittany A.; Schmink, Jason R.; Molander, Gary A.
Organic Letters, 2013 , vol. 15, # 3 p. 500 - 503
参考文献
Oliverio; Sawicki
Journal of Organic Chemistry, 1955 , vol. 20, p. 1733,1734
参考文献
E. I. du Pont de Nemours and Company
Patent: US6905630 B2, 2005 ;
Location in patent: Page/Page column 5 ;
反应条件
sodium sulfate in acetonitrile T=45°C; 2 h;
参考文献
Journal of Fluorine Chemistry, , vol. 44, p. 433 - 440
参考文献
Journal of Fluorine Chemistry, , vol. 126, # 3 p. 373 - 377
