2,2,2-三氟乙醇合成路线 (共 1089 条)
反应条件
water T=20°C; Kinetics; Further Variations:water/2,2,2-trifluoroethanol ratio dependence;
参考文献
Minegishi, Shinya; Kobayashi, Shinjiro; Mayr, Herbert
Journal of the American Chemical Society, 2004 , vol. 126, # 16 p. 5174 - 5181
反应条件
4-(N,N-dimethlyamino)pyridine; triethylamine in dichloromethane T=20°C; 16 h; Inert atmosphereCooling with ice;
参考文献
Messik, Frauke; Oberthuer, Markus
Synthesis (Germany), 2013 , vol. 45, # 2 art. no. SS-2012-T0771-PSP, p. 167 - 170
反应条件
N-ethyl-N,N-diisopropylamine 1.) in benzene, 0 deg C; 2.) 25 deg C, 1h; Yield given. Multistep reaction;
参考文献
Still, W. Clark; Gennari, Cesare
Tetrahedron Letters, 1983 , vol. 24, # 41 p. 4405 - 4408
反应条件
2,6-dimethylpyridine in water-d2 T=20°C; other O,O-dimethyl S-geranyl and S-linalyl phosphorothiolates; Product distributionRate constant;
参考文献
Journal of the American Chemical Society, , vol. 113, # 13 p. 4895 - 4903
反应条件
in water T=25°C; KineticsActivation energy;
参考文献
Gordon; Maskill
Journal of the Chemical Society, Perkin Transactions 2, 2001 , # 11 p. 2059 - 2062
反应条件
water ΔH, ΔS; Thermodynamic dataKineticsProduct distribution;
参考文献
Gordon, Isobel M.; Maskill, H.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1991 , # 12 p. 1951 - 1954
反应条件
water ΔH, ΔS; Thermodynamic dataKineticsProduct distribution;
参考文献
Gordon, Isobel M.; Maskill, H.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1991 , # 12 p. 1951 - 1954
反应条件
water ΔH, ΔS; Thermodynamic dataKineticsProduct distribution;
参考文献
Gordon, Isobel M.; Maskill, H.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1991 , # 12 p. 1951 - 1954
反应条件
T=25°C; Solvolysis; Kinetics; Concentration;
参考文献
Arkivoc, , vol. 2012, # 7 p. 25 - 34
反应条件
potassium 2,2,2-trifluoroethoxide T=30°C; μ = 0.05 M with potassium trifluoroacetate; Rate constant;
参考文献
Journal of the American Chemical Society, , vol. 115, # 23 p. 10722 - 10727