2,2,2-三氟乙醇合成路线 （共 1089 条）
反应条件
potassium 2,2,2-trifluoroethoxide T=30°C; μ = 0.05 M with potassium trifluoroacetate; Rate constant;
参考文献
Xu, Yiying; Dietze, Paul E.
Journal of the American Chemical Society, 1993 , vol. 115, # 23 p. 10722 - 10727
参考文献
Bulletin of the Chemical Society of Japan, , vol. 75, # 4 p. 789 - 800
反应条件
water T=50°C; in var. mixed aqueaus-TFE; Rate constant;
参考文献
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , p. 717 - 720
反应条件
water T=42°C; rate effects of SCN(1-) at the solvolysis; Product distribution;
参考文献
Maskill, H.; Jencks, William P.
Journal of the American Chemical Society, 1987 , vol. 109, # 7 p. 2062 - 2070
反应条件
water T=42°C; products from solvolysis , effects of ethanol and sodium thiocyanate; Product distribution;
参考文献
Maskill, H.; Jencks, William P.
Journal of the American Chemical Society, 1987 , vol. 109, # 7 p. 2062 - 2070
反应条件
water in acetone T=25°C; further ionic strength; Rate constantProduct distribution;
参考文献
Maskill, H.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 1241 - 1246
反应条件
water T=25°C; further ionic strength; Rate constantProduct distribution;
参考文献
Maskill, H.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 1241 - 1246
参考文献
Bentley, T. William; Jones, Robert O; Kang, Dae Ho; Koo, Sun
Journal of Physical Organic Chemistry, 2009 , vol. 22, # 9 p. 799 - 806
反应条件
T=50°C; various solvents, other substituted allyl arenesulfonates; Rate constant;
参考文献
Kevill, Dennis N.; Rissmann, Thomas J.
Journal of Organic Chemistry, 1985 , vol. 50, # 17 p. 3062 - 3064
反应条件
1: 2,2,2-trifluoroethanol With sodium hydride in tetrahydrofuran; mineral oil T=20°C; 0.5 h; 2: bromo-3 chloro-2 pyridine in tetrahydrofuran; mineral oil T=5 - 50°C; 48 h;
参考文献
BAYER SCHERING PHARMA AKTIENGESELLSCHAFT; KOPPITZ, Marcus; SCHULZE, Volker; KOSEMUND, Dirk; SCHIROK, Hartmut; BADER, Benjamin; LIENAU, Philipp; MARQUARDT, Tobias; WEGSCHEIDT-GERLACH, Christof; SIEMEISTER, Gerhard; PRECHTL, Stefan; WENGNER, Antje; BOeMER, Ulf
Patent: WO2011/64328 A1, 2011 ;
Location in patent: Page/Page column 104-105 ;
WO 2011/064328 A1
