2,2,2-三氟乙醇合成路线 （共 1089 条）
反应条件
T=25°C; Solvolysis; Kinetics; Concentration;
参考文献
Bentley, T. William; Koo, In Sun
Arkivoc, 2012 , vol. 2012, # 7 p. 25 - 34
反应条件
pyridine T=90°C; 0.5 h; other fluorinated alcohols; hydride shift in cyclohexyl tosylate solvolysis; Product distribution;
参考文献
Schneider, H.-J.; Busch, Rainer
Journal of Organic Chemistry, 1982 , vol. 47, # 9 p. 1766 - 1769
反应条件
T=20°C; Irradiation;
参考文献
Journal of the American Chemical Society, , vol. 118, # 32 p. 7473 - 7477
反应条件
sodium carbonate T=80°C; 216 h; Further byproducts given;
参考文献
Collins, Clair J.; Hanack, Michael; Stutz, Herbert; Auchter, Gerhard; Schoberth, Winfried
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5260 - 5268
反应条件
sodium carbonate T=25°C; 24 h; Further byproducts given;
参考文献
Collins, Clair J.; Hanack, Michael; Stutz, Herbert; Auchter, Gerhard; Schoberth, Winfried
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5260 - 5268
反应条件
sodium carbonate T=50°C; 360 h; Further byproducts given;
参考文献
Collins, Clair J.; Hanack, Michael; Stutz, Herbert; Auchter, Gerhard; Schoberth, Winfried
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5260 - 5268
反应条件
sodium hydride in N,N,N',N',N'',N''-hexamethylphosphoric triamide; hexane T=90 - 150°C;
参考文献
Gupton, John T.; Idoux, John P.; Colon, Cesar; Rampi, Rick
Synthetic Communications, 1982 , vol. 12, # 9 p. 695 - 700
反应条件
sodium hydride in N,N-dimethyl-formamide Ambient temperature;
参考文献
Zhang, Rong; Qian, Xuhong; Zhou, Weida
Organic Preparations and Procedures International, 1999 , vol. 31, # 1 p. 110 - 111
反应条件
1: 2,2,2-trifluoroethanol With sodium hydride in N,N-dimethyl-formamide 2: 4-fluorobenzenecarbonitrile in N,N-dimethyl-formamide 3 h; Reflux;
参考文献
Riss, Patrick J.; Aigbirhio, Franklin I.
Chemical Communications, 2011 , vol. 47, # 43 p. 11873 - 11875
反应条件
water T=25°C; deuterium isotope effect; Product distributionRate constant;
参考文献
Shiner, V. J.; Tai, Jimmy J.
Journal of the American Chemical Society, 1981 , vol. 103, # 2 p. 436 - 442
