2,2,2-三氟乙醇合成路线 （共 1089 条）
反应条件
sodium trifluoroethoxide
T=10 - 20°C; 0.5 h;
参考文献
Leitich, Johannes; Heise, Ingeborg
European Journal of Organic Chemistry, 2001 , # 14 p. 2707 - 2718
反应条件
sodium trifluoroethoxide
T=10 - 20°C; 0.5 h; Product distribution;
参考文献
Leitich, Johannes; Heise, Ingeborg
European Journal of Organic Chemistry, 2001 , # 14 p. 2707 - 2718
反应条件
sodium trifluoroethoxide
T=10 - 20°C; 0.5 h; Product distribution;
参考文献
Leitich, Johannes; Heise, Ingeborg
European Journal of Organic Chemistry, 2001 , # 14 p. 2707 - 2718
反应条件
T=20°C; Irradiation;
参考文献
Kirmse, Wolfgang; Krzossa, Birgit; Steenken, Steen
Journal of the American Chemical Society, 1996 , vol. 118, # 32 p. 7473 - 7477
反应条件
sodium carbonate
T=50°C; 72 h; various conc. of TFE; other solvent: EtOH; also in addition of LiBr; other temp.; ΔH(excit.), half fife time; Product distributionThermodynamic dataKinetics;
参考文献
Hanack, Michael; Rieth, Robert
Chemische Berichte, 1987 , vol. 120, p. 1659 - 1666
反应条件
triethylamine in water
T=65°C; homopropargyl rearrangement, var. of solvent, temp., ΔH(excit.); KineticsProduct distributionThermodynamic data;
参考文献
Auchter, Gerhard; Hanack, Michael
Chemische Berichte, 1982 , vol. 115, # 10 p. 3402 - 3413
反应条件
Product distribution;
参考文献
Hanack, Michael; Schuhmacher, Werner; Kunzmann, Erich
Chemische Berichte, 1982 , vol. 115, # 4 p. 1467 - 1487
反应条件
Condensation; UV-irradiation;
参考文献
Rajes, Cheruvallil S.; Givens, Richard S.; Wirz, Jakob
Journal of the American Chemical Society, 2000 , vol. 122, # 4 p. 611 - 618
反应条件
sodium hydroxide; tetrabutylammomium bromide in dichloromethane; water
T=0°C;
参考文献
BRISTOL-MYERS SQUIBB COMPANY; SUN, Li-Qiang; MULL, Eric; ZHAO, Qian; WANG, Tao; ZHANG, Zhongxing; SCOLA, Paul Michael
Patent: WO2012/24373 A1, 2012 ;
Location in patent: Page/Page column 32 ;
反应条件
T=25°C; 0.05 h; UV-irradiation; Title compound not separated from byproducts;
参考文献
Roberts, Jeffrey C.; Pincock, James A.
Journal of Organic Chemistry, 2006 , vol. 71, # 4 p. 1480 - 1492
