2,2,2-三氟乙醇合成路线 （共 1089 条）
反应条件
T=25°C; 0.0333333 h; UV-irradiation; Title compound not separated from byproducts;
参考文献
Roberts, Jeffrey C.; Pincock, James A.
Journal of Organic Chemistry, 2006 , vol. 71, # 4 p. 1480 - 1492
反应条件
water
T=20°C; Flash photolysis; Kinetics; Further Variations:water/2,2,2-trifluoroethanol ratio dependence;
参考文献
Minegishi, Shinya; Kobayashi, Shinjiro; Mayr, Herbert
Journal of the American Chemical Society, 2004 , vol. 126, # 16 p. 5174 - 5181
反应条件
water
T=20°C; Flash photolysis; Kinetics;
参考文献
Minegishi, Shinya; Kobayashi, Shinjiro; Mayr, Herbert
Journal of the American Chemical Society, 2004 , vol. 126, # 16 p. 5174 - 5181
反应条件
water
T=20°C; Kinetics; Further Variations:water/2,2,2-trifluoroethanol ratio dependence;
参考文献
Minegishi, Shinya; Kobayashi, Shinjiro; Mayr, Herbert
Journal of the American Chemical Society, 2004 , vol. 126, # 16 p. 5174 - 5181
反应条件
sodium hydrogencarbonate in acetone
T=20°C; 4 h;
参考文献
Tanaka, Tomonari; Noguchi, Masato; Watanabe, Kazuhito; Misawa, Takuya; Ishihara, Masaki; Kobayashi, Atsushi; Shoda, Shin-Ichiro
Organic and Biomolecular Chemistry, 2010 , vol. 8, # 22 p. 5126 - 5132
反应条件
sodium hydroxide; tetrabutyl-ammonium chloride in dichloromethane
T=0 - 3°C; 0.25 h;
参考文献
Sitzmann, Michael E.; Gilligan, William H.
Journal of Organic Chemistry, 1983 , vol. 48, # 19 p. 3354 - 3356
反应条件
in tetrahydrofuran; water
参考文献
KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY
Patent: EP966466 B1, 2002 ;
反应条件
tetrabutyl ammonium fluoride in N,N-dimethyl-formamide
T=20°C; 1.5 h;
参考文献
Tejero, Ismael; Huertas, Imma; Gonzalez-Lafont, Angels; Lluch, Jose M.; Marquet, Jordi
Journal of Organic Chemistry, 2005 , vol. 70, # 5 p. 1718 - 1727
反应条件
1: 2,2,2-trifluoroethanol With sodium hydride in N,N-dimethyl-formamide
T=5 - 20°C; 1 h;
2: 2-fluoro-1-nitrobenzene in N,N-dimethyl-formamide
T=20°C; 2 h;
参考文献
MITSUI CHEMICALS, INC.
Patent: WO2006/137395 A1, 2006 ;
Location in patent: Page/Page column 141 ;
反应条件
tetrabutyl ammonium fluoride in N,N-dimethyl-formamide
T=20°C; 3 h;
参考文献
Tejero, Ismael; Huertas, Imma; Gonzalez-Lafont, Angels; Lluch, Jose M.; Marquet, Jordi
Journal of Organic Chemistry, 2005 , vol. 70, # 5 p. 1718 - 1727
