2,2,2-三氟乙醇合成路线 （共 1089 条）
反应条件
T=25°C; 0.0333333 h; UV-irradiation; Title compound not separated from byproducts;
参考文献
Roberts, Jeffrey C.; Pincock, James A.
Journal of Organic Chemistry, 2006 , vol. 71, # 4 p. 1480 - 1492
反应条件
sodium
1.) ice cooling to room temperature; 2.) 150 deg C, 14 h, autoclave; Multistep reaction;
参考文献
Carroll; Berrang; Linn
Journal of Heterocyclic Chemistry, 1981 , vol. 18, # 5 p. 941 - 946
反应条件
water in acetonitrile
T=25°C; solvolytic reaction; role of nucleophilic and other solvation effects; ΔH(activ.), ΔS(activ.); further temp. 39.9 deg C; Rate constantThermodynamic data;
参考文献
Bentley, T. William; Llewellyn, Gareth; Ryu, Zoon Ha
Journal of Organic Chemistry, 1998 , vol. 63, # 14 p. 4654 - 4659
反应条件
water
T=25°C; solvolytic reaction; role of nucleophilic and other solvation effects; Rate constant;
参考文献
Bentley, T. William; Llewellyn, Gareth; Ryu, Zoon Ha
Journal of Organic Chemistry, 1998 , vol. 63, # 14 p. 4654 - 4659
反应条件
water
T=25°C; solvolytic reaction; role of nucleophilic and other solvation effects; Rate constant;
参考文献
Bentley, T. William; Llewellyn, Gareth; Ryu, Zoon Ha
Journal of Organic Chemistry, 1998 , vol. 63, # 14 p. 4654 - 4659
反应条件
triethylamine in acetone
T=20°C; 1 h;
参考文献
Lopez, Moises Canle; Demirtas, Ibrahim; Maskill, Howard; Mishima, Masaaki
Journal of Physical Organic Chemistry, 2008 , vol. 21, # 7-8 p. 614 - 621
参考文献
Canle L., Moises; Maskill, Howard
Journal of Physical Organic Chemistry, 2013 , vol. 26, # 12 p. 1016 - 1022
反应条件
copper(l) iodide; di-tert-butyl peroxide; nacnacXylH in neat (no solvent)
T=90°C; 6 h; Sealed tubeInert atmosphere;
参考文献
Zhu, Yefeng; Wei, Yunyang
European Journal of Organic Chemistry, 2013 , # 21 p. 4503 - 4508
反应条件
triethylamine in diethyl ether
参考文献
Liepin'sh, E. E.; Zitsmane, I. A.; Ignatovich, L. M.; Lukevits, E.; Guvanova, L. I.; Voronkov, M. G.
J. Gen. Chem. USSR (Engl. Transl.), 1983 , vol. 53, # 8 p. 1789 - 1792,1609 - 1612
反应条件
iodine; potassium carbonate
T=50°C; 14 h;
参考文献
Mori, Naoshi; Togo, Hideo
Tetrahedron, 2005 , vol. 61, # 24 p. 5915 - 5925
