2,2,2-三氟乙醇合成路线 （共 1089 条）
反应条件
in acetonitrile
T=25°C; various composition of trifluoroethanol/ethanol; solvolytic reaction; role of nucleophilic and other solvation effects; product selectivity; Rate constant;
参考文献
Bentley, T. William; Llewellyn, Gareth; Ryu, Zoon Ha
Journal of Organic Chemistry, 1998 , vol. 63, # 14 p. 4654 - 4659
反应条件
tetraethylammonium tetrafluoroborate
T=-10°C; Oxidation; Electrochemical reaction;
参考文献
Shirai, Kimihiro; Onomura, Osamu; Maki, Toshihide; Matsumura, Yoshihiro
Tetrahedron Letters, 2000 , vol. 41, # 31 p. 5873 - 5876
反应条件
toluene-4-sulfonic acid
T=20°C; Substitution;
参考文献
Shirai, Kimihiro; Onomura, Osamu; Maki, Toshihide; Matsumura, Yoshihiro
Tetrahedron Letters, 2000 , vol. 41, # 31 p. 5873 - 5876
反应条件
in acetonitrile
T=25°C; various composition of trifluoroethanol/ethanol; solvolytic reaction; role of nucleophilic and other solvation effects; product selectivity; Rate constant;
参考文献
Bentley, T. William; Llewellyn, Gareth; Ryu, Zoon Ha
Journal of Organic Chemistry, 1998 , vol. 63, # 14 p. 4654 - 4659
反应条件
in m-xylene
T=60°C; 1 h;
参考文献
Lee, Bora; Kim, Jin Hyung; Lee, Hyunjoo; Ahn, Byoung Sung; Cheong, Minserk; Kim, Hoon Sik; Kim, Honggon
Journal of Fluorine Chemistry, 2007 , vol. 128, # 2 p. 110 - 113
反应条件
sodium saccharine
T=80 - 90°C; 2 h;
参考文献
Zhang, Y. F.; Kirchmeier, Robert L.; Shreeve, Jean'ne M.
Journal of Fluorine Chemistry, 1994 , vol. 68, # 3 p. 287 - 292
反应条件
T=25°C; other temperature (50 deg C); solvolysis of β-silyl systems, conformation effect; Rate constant;
参考文献
Lambert, Joseph B.; Finzel, Rodney B.
Journal of the American Chemical Society, 1982 , vol. 104, # 7 p. 2020 - 2022
反应条件
T=25°C; solvolysis of β-silyl systems; Rate constant;
参考文献
Lambert, Joseph B.; Finzel, Rodney B.
Journal of the American Chemical Society, 1982 , vol. 104, # 7 p. 2020 - 2022
反应条件
sodium hydride in N,N,N',N',N'',N''-hexamethylphosphoric triamide; hexane
T=90 - 150°C;
参考文献
Gupton, John T.; Idoux, John P.; Colon, Cesar; Rampi, Rick
Synthetic Communications, 1982 , vol. 12, # 9 p. 695 - 700
参考文献
Hanzlik,R.P.; Hilbert,J.M.
Journal of Organic Chemistry, 1978 , vol. 43, # 4 p. 610 - 614
