1-苄基-2-(氯甲基)苯合成路线 （共 12 条）
反应条件
magnesium anschliessend Behandeln mit CO2;
参考文献
Bristol Labor. Inc.
Patent: US759934 , 1953 ;
反应条件
pyridine; thionyl chloride
4 h; Heating;
参考文献
Van Herwijnen; Brinker
Journal of Organic Chemistry, 2001 , vol. 66, # 8 p. 2874 - 2876
反应条件
lithium tetrakis(pentafluorophenyl)-borate
T=20°C; Friedel-Crafts benzylation; 10 h;
参考文献
Mukaiyama, Teruaki; Nakano, Masakazu; Kikuchi, Wataru; Matsuo, Jun-Ichi
Chemistry Letters, 2000 , # 9 p. 1010 - 1011
反应条件
1: 76 percent / H2 / Pd/C / acetic acid / 44 h / 65 °C / 750.08 Torr
2: 76 percent / LAH / diethyl ether / 1 h / Heating
3: 84 percent / SOCl2; pyridine / 4 h / Heating
View Scheme
参考文献
Van Herwijnen; Brinker
Journal of Organic Chemistry, 2001 , vol. 66, # 8 p. 2874 - 2876
反应条件
1: 76 percent / LAH / diethyl ether / 1 h / Heating
2: 84 percent / SOCl2; pyridine / 4 h / Heating
View Scheme
参考文献
Van Herwijnen; Brinker
Journal of Organic Chemistry, 2001 , vol. 66, # 8 p. 2874 - 2876
反应条件
aluminium trichloride; nitrobenzene
T=-15°C;
参考文献
Wertyporoch; Farnik
Justus Liebigs Annalen der Chemie, 1931 , vol. 491, p. 265,271
反应条件
sulfur
T=230°C; 4 h; Further byproducts given;
参考文献
Przewoski, K.; Voronkov, M. G.; Przewoska, L.; Warnke, Z.; Szafranek, J.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1989 , vol. 38, # 3.2 p. 579 - 580
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1989 , # 3 p. 653 - 654
反应条件
NaY zeolite in pentane
T=20°C; Friedel-Crafts reaction; Product distribution; Further Variations:ReagentsTemperatures;
参考文献
Van Herwijnen; Brinker
Journal of Organic Chemistry, 2001 , vol. 66, # 8 p. 2874 - 2876
反应条件
NaY zeolite in pentane
T=20°C; 2 h; Product distribution; Further Variations:Reagentstime dependence;
参考文献
Van Herwijnen, Hendrikus W.G; Brinker, Udo H
Tetrahedron, 2002 , vol. 58, # 24 p. 4963 - 4967
反应条件
sulfur
T=230°C; 4 h; other time (1 h); further products identified; Product distribution;
参考文献
Przewoski, K.; Voronkov, M. G.; Przewoska, L.; Warnke, Z.; Szafranek, J.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1989 , vol. 38, # 3.2 p. 579 - 580
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1989 , # 3 p. 653 - 654
