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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
75203-87-1
合成路线
（共 9 条）
186451-82-1
→
反应条件
75203-87-1
反应条件
sodium tetrahydroborate in ethanol; dichloromethane T=-78 - 20°C;
参考文献
Takikawa, Hirosato; Hosoe, Shintaro; Ueda, Keiko; Sasaki, Mitsuru
Bioscience, biotechnology, and biochemistry, 2004 , vol. 68, # 9 p. 1961 - 1965
472-65-1
→
反应条件
83646-52-0
+
75203-87-1
反应条件
pyridine 1-oxide; selenium(IV) oxide in 1,4-dioxane T=85°C; 6 h;
参考文献
Aranda, Gerard; Bertranne-Delahaye, Mireille; Azerad, Robert; Maurs, Michele; Cortes, Manuel; Ramirez, Hector; Vernal, Gonzalo; Prange, Thierry
Synthetic Communications, 1997 , vol. 27, # 1 p. 45 - 60
83646-52-0
→
反应条件
75203-87-1
反应条件
manganese(IV) oxide in chloroform T=20°C; 43 h;
参考文献
Takikawa, Hirosato; Hosoe, Shintaro; Ueda, Keiko; Sasaki, Mitsuru
Bioscience, biotechnology, and biochemistry, 2004 , vol. 68, # 9 p. 1961 - 1965
825614-90-2
→
反应条件
75203-87-1
反应条件
1: 86 percent / OsO4; N-methylmorpholine N-oxide / acetone; H2O; 2-methyl-propan-2-ol / 20 °C 2: 93 percent / NaIO4 / diethyl ether; H2O / 1 h 3: 91 percent / LiAlH4 / tetrahydrofuran / 0 °C 4: 56 percent / MnO2 / CHCl3 / 43 h / 20 °C View Scheme
参考文献
Takikawa, Hirosato; Hosoe, Shintaro; Ueda, Keiko; Sasaki, Mitsuru
Bioscience, biotechnology, and biochemistry, 2004 , vol. 68, # 9 p. 1961 - 1965
825614-92-4
3-(2,3-二羟基丙基)-2,4,4-三甲基-2-环己烯-1-酮
→
反应条件
75203-87-1
反应条件
1: 93 percent / NaIO4 / diethyl ether; H2O / 1 h 2: 91 percent / LiAlH4 / tetrahydrofuran / 0 °C 3: 56 percent / MnO2 / CHCl3 / 43 h / 20 °C View Scheme
参考文献
Takikawa, Hirosato; Hosoe, Shintaro; Ueda, Keiko; Sasaki, Mitsuru
Bioscience, biotechnology, and biochemistry, 2004 , vol. 68, # 9 p. 1961 - 1965
60068-02-2
→
反应条件
75203-87-1
反应条件
1.1: Mg; iodine / diethyl ether / 0 - 20 °C 1.2: 88 percent / diethyl ether; tetrahydrofuran / 20 °C 2.1: 86 percent / OsO4; N-methylmorpholine N-oxide / acetone; H2O; 2-methyl-propan-2-ol / 20 °C 3.1: 93 percent / NaIO4 / diethyl ether; H2O / 1 h 4.1: 91 percent / LiAlH4 / tetrahydrofuran / 0 °C 5.1: 56 percent / MnO2 / CHCl3 / 43 h / 20 °C View Scheme
参考文献
Takikawa, Hirosato; Hosoe, Shintaro; Ueda, Keiko; Sasaki, Mitsuru
Bioscience, biotechnology, and biochemistry, 2004 , vol. 68, # 9 p. 1961 - 1965
58937-20-5
→
反应条件
15356-74-8
二氢猕猴桃内酯
+
472-65-1
反应条件
sodium nitrate; potassium dihydrogenphosphate; D-glucose; cornsteep liquor; Lasiodiplodia theobromae ATCC 28570; potassium chloride in ethanol T=28°C; biotransformation;
参考文献
Krasnobajew, Victor; Helmlinger, Daniel
Helvetica Chimica Acta, 1982 , vol. 65, # 5 p. 1590 - 1601
472-65-1
→
反应条件
60814-40-6
反应条件
sodium nitrate; potassium dihydrogenphosphate; D-glucose; cornsteep liquor; Lasiodiplodia theobromae ATCC 28570; potassium chloride in ethanol T=28°C; 72 h; biotransformation;
参考文献
Krasnobajew, Victor; Helmlinger, Daniel
Helvetica Chimica Acta, 1982 , vol. 65, # 5 p. 1590 - 1601
79-77-6
β-紫罗酮
→
反应条件
17283-81-7
BETA-二氢紫罗兰酮
+
60814-40-6
+
472-65-1
反应条件
sodium nitrate; potassium dihydrogenphosphate; D-glucose; cornsteep liquor; Lasiodiplodia theobromae ATCC 28570; potassium chloride in water T=28°C; 96 h; biotransformation at pH=6.2-6.5; Mechanism;
参考文献
Krasnobajew, Victor; Helmlinger, Daniel
Helvetica Chimica Acta, 1982 , vol. 65, # 5 p. 1590 - 1601
