2-溴-[1,1:2,1]四苯合成路线 (共 5 条)
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in ethylene glycol dimethyl ether; ethanol
T=85°C; 72 h;
参考文献
Aranyos, Attila; Old, David W.; Kiyomori, Ayumu; Wolfe, John P.; Sadighi, Joseph P.; Buchwald, Stephen L.
Journal of the American Chemical Society, 1999 , vol. 121, # 18 p. 4369 - 4378
反应条件
potassium fluoride; 18-crown-6 ether; copper(ll) bromide in ethylene glycol dimethyl ether
T=25 - 80°C; 39 h;
参考文献
Morishita, Takami; Yoshida, Hiroto; Ohshita, Joji
Chemical Communications, 2010 , vol. 46, # 4 p. 640 - 642
反应条件
palladium diacetate; caesium carbonate; P(3,5-2F3C-C6H3)3 in toluene
T=110°C; 24 h; Reagent/catalyst;
参考文献
Iwasaki, Masayuki; Iino, Shohei; Nishihara, Yasushi
Organic Letters, 2013 , vol. 15, # 20 p. 5326 - 5329
反应条件
1: With tert.-butyl lithium in tetrahydrofuran; diethyl ether; pentane
T=-120 - 20°C; 0.666667 h;
2: With hydrogenchloride; ethanol in tetrahydrofuran; diethyl ether; pentane
T=-120 - -110°C; 0.5 h; Further stages. Further byproducts.;
参考文献
Bettinger, Holger F.; Filthaus, Matthias
Journal of Organic Chemistry, 2007 , vol. 72, # 25 p. 9750 - 9752
反应条件
in tetrahydrofuran
T=-90°C; 0.5 h; var. temperature; thermal decomposition; Product distributionMechanism;
参考文献
Chen, Loomis S.; Chen, Grace J.; Tamborski, Christ
Journal of Organometallic Chemistry, 1980 , vol. 193, # 3 p. 283 - 292