in dichloromethane addn. of C6H5BCl2 in CH2Cl2 to soln. of stannabicycloheptane in CH2Cl2 at -10°C; refluxing for 3 h; removing of solvent in vacuum; heating residue in boiling tolene for 72 h; removing of toluene;; sublimation at 25°C/ 1E-6 Torr with isolation of (CH3)2SnCl2 and at 85°C/ 1E-6 Torr with isolation of borabicycloheptane; contaminated;;
参考文献
Linti, Gerhard; Noeth, Heinrich; Schneider, Ellen; Storch, Wolfgang
Chemische Berichte, 1993 , vol. 126, # 3 p. 619 - 630
hydrogenchloride in methanol Kinetics; 8.5 M aq. HCl was added to a methanol soln. of the stannane in a NMR tube, reaction was followed by (1)H NMR spectroscopy for 50 h; 70percent of the substrate has been consumed, rate consts. according to different reaction paths are given; further products; not isolated, identified by (1)H NMR spectrum;
参考文献
Journal of Organometallic Chemistry, , vol. 287, p. 7 - 24
in hexane; pentane inert atmosphere, addn. of hexane soln. of BCl3 to pentane soln. of stannyl compound at -40°C with stirring; separation of precipitate (-40°C), removement of solvent (vacuum), not separated, spectroscopic yield: chlorodimethylstannylbenzene/dichloroborylbenzene/diboraanthracene 65 mol-65/percent45percent mol-percent/10percent mol-percent;
参考文献
European Journal of Inorganic Chemistry, , # 6 p. 761 - 769
