CF3SO3H in toluene byproducts: Cl(SiMe2)4Cl, (-OSiMe2SiMe2-)x; (inert atmosphere); addn. of CF3SO3H to the Sn compd. in toluene at -20°C, stirring (2 h), addn. of excess LiCl; filtration, solvent removal, NMR monitoring;
参考文献
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, , vol. 54, # 2 p. 278 - 287
in methanol Kinetics; rapid exchange process, line broadening was monitored by (1)H NMR spectroscopy at 12 min intervals during 96 min of reaction; rate const. is given; (1)H NMR data;
参考文献
Journal of Organometallic Chemistry, , vol. 287, p. 25 - 38
in tetrahydrofuran byproducts: Hg, ClSi6(CH3)11; to THF-soln. of HgCl2 THF-soln. of (CH3)2Sn(Si6(CH3)11)2 added slowly atroom temp. in 2 hs, stirring 4 hs; solvent removed in vac., sublimation;
参考文献
Journal of Organometallic Chemistry, , vol. 605, # 1 p. 22 - 27
