in diethyl ether; pentane
addn. of soln. of Me3SnCl to soln. of Li-compound (prepd. in situ) at -120°C, warming to room temp.; shaking with water, drying and concn. of org. phase; anal. and GC;
参考文献
Eikema Hommes, Nicolaas J. R.; Bickelhaupt, Friedrich; Klumpp, Gerhard W.
Angewandte Chemie, 1988 , vol. 100, # 8 p. 1100 - 1107
Zavgorodnii, V. S.; Zubova, T. P.; Simin, V. B.; Petrov, A. A.
Journal of General Chemistry USSR (English Translation), 1981 , vol. 51, p. 1765 - 1773
Zhurnal Obshchei Khimii, 1981 , vol. 51, p. 2048 - 2057
dichloro bis(acetonitrile) palladium(II) in N,N-dimethyl-formamide
T=20°C; 0.166667 h;
参考文献
Bumagin, N. A.; Bumagina, I. G.; Beletskaya, I. P.
Doklady Chemistry, 1984 , vol. 274, p. 39 - 42
Doklady Akademii Nauk SSSR, 1984 , vol. 274, # 4 p. 818 - 822
in neat (no solvent)
byproducts: ethylenebis(diphenylphosphine); under protective gas mixt. of (CH3)3SnCHCH2 and (C6H5)2PH in presence of AIBN without solvent, heated at 80-90°C during 10 h;
参考文献
Weichmann, H.; Quell, G.; Tzschach, A.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1980 , vol. 462, p. 7 - 17
in tetrahydrofuran
dry Ar atmosphere; Yb-Grignard preparation form Yb and iodide in THF; addn. of Sn-compd. soln., stirring (2 h), decomposition with saturated NH4Cl soln.; extraction by ether, ether removal, distillation of residue;
参考文献
Rybakova; Starostina; Syutkina; Petrov
Russian Journal of General Chemistry, 1996 , vol. 66, # 4 p. 575 - 577
