(S)-(-)-β-香茅醇合成路线 （共 44 条）
反应条件
Candida viswanathii IFO 10321 in various solvent(s) T=30°C; 240 h; Microbiological reaction;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 73, # 12 p. 2819 - 2823
反应条件
3,7-dimethyl-trans-2,6-octadien-1-ol; copper T=220°C; P=30 Torr;
参考文献
Doeuvre
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1939 , vol. 208, p. 1659
Bulletin de la Societe Chimique de France, 1940 , vol. <5>7, p. 142,143
反应条件
1: bromine; Na2CO3 / 4 h / 5 - 10 °C 2: KOH; Aliquat(TM) / acetonitrile / 16 h / Heating 3: aq. hydrochloric acid / hexane 4: 37 percent Turnov. / palladium(II) acetate; (S)-BINAP / 16 h / 20 °C View Scheme
参考文献
Yamamoto, Takeshi; Matsuda, Hiroyuki; Utsumi, Yasuhide; Hagiwara, Toshimitsu; Kanisawa, Tsuneyoshi
Tetrahedron Letters, 2002 , vol. 43, # 50 p. 9077 - 9080
反应条件
pyridine-SO3 complex; dimethyl sulfoxide; triethylamine in dichloromethane 15 h;
参考文献
Dawson, Glenn W.; Pickett, John A.; Smiley, Diane W. M.
Bioorganic and Medicinal Chemistry, 1996 , vol. 4, # 3 p. 351 - 361
反应条件
3,7-dimethyl-trans-2,6-octadien-1-ol; copper T=220°C; P=30 Torr;
参考文献
Doeuvre
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1939 , vol. 208, p. 1659
Bulletin de la Societe Chimique de France, 1940 , vol. <5>7, p. 142,143
反应条件
dipyridinium dichromate in dichloromethane Title compound not separated from byproducts;
参考文献
Cornia, Mara; Casiraghi, Giovanni; Casnati, Giuseppe; Zetta, Lucia
Gazzetta Chimica Italiana, 1989 , vol. 119, # 6 p. 329 - 334
反应条件
1.1: Et3N 2.1: NaBr / dimethylformamide 3.1: MCPBA / CHCl3 3.2: NaIO4 / tetrahydrofuran; H2O View Scheme
参考文献
Shimizu, Yuko; Kiyota, Hiromasa; Oritani, Takayuki
Tetrahedron Letters, 2000 , vol. 41, # 17 p. 3141 - 3144
反应条件
dipyridinium dichromate in dichloromethane Title compound not separated from byproducts;
参考文献
Cornia, Mara; Casiraghi, Giovanni; Casnati, Giuseppe; Zetta, Lucia
Gazzetta Chimica Italiana, 1989 , vol. 119, # 6 p. 329 - 334
反应条件
1: 97 percent / SO3*pyridine, Et3N, DMSO / CH2Cl2 / 15 h 2: 43 percent / SeO2, t-BuOOH / 2,2,4-trimethyl-pentane; CH2Cl2 / 48 h 3: 67 percent / molecular sieves 4 Angstroem / diethyl ether / 10 h 4: 86 percent / p-TsOH*H2O, H2O / tetrahydrofuran / 1 h 5: 60 percent / silver carbonate, Celite / benzene / 2 h / Heating View Scheme
参考文献
Dawson, Glenn W.; Pickett, John A.; Smiley, Diane W. M.
Bioorganic and Medicinal Chemistry, 1996 , vol. 4, # 3 p. 351 - 361
反应条件
1: 97 percent / SO3*pyridine, Et3N, DMSO / CH2Cl2 / 15 h
2: 43 percent / SeO2, t-BuOOH / 2,2,4-trimethyl-pentane; CH2Cl2 / 48 h
3: 67 percent / molecular sieves 4 Angstroem / diethyl ether / 10 h
4: 86 percent / p-TsOH*H2O, H2O / tetrahydrofuran / 1 h
View Scheme
参考文献
Dawson, Glenn W.; Pickett, John A.; Smiley, Diane W. M.
Bioorganic and Medicinal Chemistry, 1996 , vol. 4, # 3 p. 351 - 361
