in n-heptane byproducts: CH3C6H5; under purified Ar atm.; soln. of TiCl4 in heptane added to soln. of Ti(η6-MeC6H5)2 in heptane; mixt. stirred for 18 h at room temp.; solid filtered; washed (heptane); dried (vac.); elem. anal.;
参考文献
Calderazzo, Fausto; Englert, Ulli; Pampaloni, Guido; Volpe, Manuel
Journal of Organometallic Chemistry, 2005 , vol. 690, # 14 p. 3321 - 3332
hydrogen in gas byproducts: HCl; Irradiation (UV/VIS); in a laser powder synthesis cell; 1100°C; X-ray diffraction; transmission electron microscopy; single point BET surface area analysis; thermal gravimetric analysis; differential thermalanalysis; atomic absorption spectroscopy;
参考文献
Casey; Haggerty
Journal of Materials Science, 1987 , vol. 22, # 2 p. 737 - 744
chlorine burning a flame of Cl2 and TiCl4-vapor in hydrogen atmosphere;
参考文献
Meyer, F.; Kerstein
Ber., 1914 , vol. 47, p. 1036
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Meyer, F.
Ber., 1912 , vol. 45, p. 2548
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Gmelin Handbook: H: MVol., 1.6.1, page 212 - 219
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Meyer, F.
Patent: DE261922 , 1913 ;
in gas Irradiation (UV/VIS); in a laser powder synthesis cell; 1330-1530°C; various yields for various conditions; X-ray diffraction; transmission electron microscopy; single point BET surface area analysis; thermal gravimetric analysis; differential thermalanalysis; atomic absorption spectroscopy;
参考文献
Casey; Haggerty
Journal of Materials Science, 1987 , vol. 22, # 2 p. 737 - 744
in water reaction of TiCl4 with aq. Na2S2O4 forming TiCl3, NaCl and SO2; equilibrium reaction; forward reaction preferenced in an acidic soln. with an excess of Na2S2O4; reverse reaction preferenced in an alkaline soln.;;
in gas Kinetics; byproducts: HCl; Irradiation (UV/VIS); stationary photolysis in a sealed quartz cell at 210°C; vac.distn.;
参考文献
Skorobogatov, G. A.; Dymov, B. P.; Dzevitskii. B. E.; Busov, S. N.; Bryukvin, V. A.
Journal of General Chemistry USSR (English Translation), 1983 , vol. 53, p. 1 - 5
Zhurnal Obshchei Khimii, 1983 , vol. 53, p. 9 - 14
