mercury dibromide in carbon disulfide under N2, reaction of P4 with I2, followed by treatment of the soln. with HgBr2, further products Br2P2I2, BrIP2BrI, BrIP2I2 and P2I4; not isolated, identified by 31P-NMR spectroscopy;
参考文献
Tattershall, Bruce W.; Kendall, Nigel L.
Polyhedron, 1994 , vol. 13, p. 1517 - 1522
in neat (no solvent) heating to 180°C with pptn. of PI3, after fractionating for 24 h there is formation of PI2(CF3) and PI(CF3)2;;
参考文献
Bennet, F. W.; Emeleus, H. J.; Haszeldine, R. N.
Journal of the Chemical Society, 1953 , p. 1565 - 1571
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Gmelin Handbook: P: MVol.C, 271, page 622 - 624
in dichloromethane-d2 Sonication; I2 was sublimed into an NMR tube with complex at 77 K after CD2Cl2, NMR tube was sealed, activated with ultrasound at -78°C for about 10 min; not sepd., detected by NMR spectra;
参考文献
Krossing, Ingo
Journal of the Chemical Society, Dalton Transactions, 2002 , # 4 p. 500 - 512
in dichloromethane Sonication; to a Ag-compound P4 in CS2 was added at room temp., volatiles were removed, dissolved in CH2Cl2, I2 was sublimed into the mixt., the soln. was stirred overnight at -30°C; volatiles were removed in vac., extd. with CS2 at room temp.;
参考文献
Krossing, Ingo
Journal of the Chemical Society, Dalton Transactions, 2002 , # 4 p. 500 - 512
Pelabon H.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1929 , vol. 189, p. 1085 - 1087
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Gmelin Handbook: P: MVol.B, 3.4.1.6, page 282 - 285
