in gas
Kinetics; Irradiation (UV/VIS); photodissociaton of (CD3I)2 at 248 nm and at 500 mTorr in presence of CO2, Ar, Xe, O2, N2, Kr or He;; not isolated; detection of I2 by laser induced fluorescence;;
参考文献
Fan, Y. B.; Donaldson, D. J.
Journal of Chemical Physics, 1992 , vol. 97, # 1 p. 189 - 196
Davison, A.; Reger. D. L.
Journal of Organometallic Chemistry, 1970 , vol. 23, p. 491 - 496
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Gmelin Handbook: V: Org.Verb., 1.5.1, page 49 - 50
water in not given
react. of a soln. of 5 ml 0.025 n NaH2PO2 and 25 ml 0.1 n NaICl4 at 60-70 °C;; 80.3 percent H3PO2 are oxidized after 1 h, 80.9 percent after 2 h and 99.9 percent after 42 h;;
参考文献
Fialkov, Ya. F.; Kagan, F. E.
Zh. obshchei Khim., 1954 , vol. 24, p. 3 - 10
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Gmelin Handbook: P: MVol.C, 53, page 112 - 113
in water
Kinetics; byproducts: H2O, H(1+); 0.002-0.85 M acetate buffer (pH 3.50-5.00, μ=0.50 M (NaClO4), 25°C; not isolated, reaction followed by UV/VIS spectroscopy;
参考文献
Urbansky, Edward T.; Cooper, Brian T.; Margerum, Dale W.
Inorganic Chemistry, 1997 , vol. 36, # 7 p. 1338 - 1344
sulfuric acid in water
effect of freezing investigated by freezing pre-acidified soln. of NO2(1-) and I(1-) ions at pH values between 1.5 and 3.0; H2SO4 used to acidify the system; NaBr added as bromide ion source; not isolated; detected by UV-VIS spectroscopy;
参考文献
O'Driscoll, Paul; Lang, Kathrin; Minogue, Nicholas; Sodeau, John
Journal of Physical Chemistry A, 2006 , vol. 110, # 14 p. 4615 - 4618
sulfuric acid in water
effect of freezing investigated by freezing pre-acidified soln. of NO2(1-) and I(1-) ions at pH values between 1.5 and 3.0; H2SO4 used to acidify the system; NaCl added as chloride ion source; not isolated; detected by UV-VIS spectroscopy;
参考文献
O'Driscoll, Paul; Lang, Kathrin; Minogue, Nicholas; Sodeau, John
Journal of Physical Chemistry A, 2006 , vol. 110, # 14 p. 4615 - 4618
sodium hydroxide in water
Kinetics; mixing peroxynitrite (0.01 M NaOH) with NaI (0.2 M phosphate buffer at pH 5.8 and at pH 3.2); absorbance at 350 nm;
参考文献
Kurz, Christophe; Zeng, Xiuqiong; Hannemann, Stefan; Kissner, Reinhard; Koppenol, Willem H.
Journal of Physical Chemistry A, 2005 , vol. 109, # 6 p. 965 - 969
