(3-甲基-1,2-恶唑-5-基)甲基-三苯基磷鎓氯化物合成路线 （共 4 条）
反应条件
hydroxylamine hydrochloride in water
1.) room temp., 16 h, 2.) reflux, 4 h;
参考文献
Oehler, Elisabeth; Zbiral, Erich
Chemische Berichte, 1980 , vol. 113, # 9 p. 2852 - 2867
反应条件
1: 1 N HCl / 3 h / Heating
2: 71 percent / NH2OH*HCl / H2O / 1.) room temp., 16 h, 2.) reflux, 4 h
View Scheme
参考文献
Oehler, Elisabeth; Zbiral, Erich
Chemische Berichte, 1980 , vol. 113, # 9 p. 2852 - 2867
反应条件
1: 1.) n-BuLi / 1.) THF, hexane, -30 deg C, 90 min, 2.) THF, -30 deg C, 2 h
2: 1 N HCl / 3 h / Heating
3: 71 percent / NH2OH*HCl / H2O / 1.) room temp., 16 h, 2.) reflux, 4 h
View Scheme
参考文献
Oehler, Elisabeth; Zbiral, Erich
Chemische Berichte, 1980 , vol. 113, # 9 p. 2852 - 2867
反应条件
1: 75 percent / CH2Cl2 / 96 h / Ambient temperature
2: 1.) n-BuLi / 1.) THF, hexane, -30 deg C, 90 min, 2.) THF, -30 deg C, 2 h
3: 1 N HCl / 3 h / Heating
4: 71 percent / NH2OH*HCl / H2O / 1.) room temp., 16 h, 2.) reflux, 4 h
View Scheme
参考文献
Oehler, Elisabeth; Zbiral, Erich
Chemische Berichte, 1980 , vol. 113, # 9 p. 2852 - 2867
