in neat (no solvent)
Kinetics; Irradiation (UV/VIS); photolysis at 27-285°C and 240-253.7 nm; mechanism discussed; further products;; yields of CH4 and C2H6 depending on temp.;;
参考文献
Ausloos, P.; Steacie, E. W. R.
Canadian Journal of Chemistry, 1955 , vol. 33, p. 1530 - 1535
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Gmelin Handbook: C: MVol.C4, 6.4.5.2, page 162 - 163
Bak
Journal of Organic Chemistry, 1956 , vol. 21, p. 797
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Schissler et al.
Discussions of the Faraday Society, 1951 , vol. 10, p. 46,47
Bak
Journal of Organic Chemistry, 1956 , vol. 21, p. 797
Full Text View citing articles Show Details
Schissler et al.
Discussions of the Faraday Society, 1951 , vol. 10, p. 46,47
in tetrahydrofuran
byproducts: CO; Stirring of THF soln. of starting materials with CH3COOH (3 days, room temp., N2 or Ar).; Evolution of CO obsd. (gas chromy.), IR identification of dimer anion in soln. Filtn. of soln. affords org. compd.;
in gaseous matrix
in He at 300K, isotopic labeling studied; MS, not isolated;
参考文献
Gronert, Scott; O'Hair, Richard A. J.; Prodnuk, Stephen; Suelzle, Detlev; Damrauer, Robert; DePuy, Charles H.
Journal of the American Chemical Society, 1990 , vol. 112, p. 998 - 1003
Katritzky, Alan R.; Dega-Szafran, Zofia; Lopez-Rodriguez, Maria L.; King, Roy W.
Journal of the American Chemical Society, 1984 , vol. 106, # 19 p. 5577 - 5585
