N-(3-苯基-2-丙基)苯胺合成路线 （共 20 条）
反应条件
borane-THF; phthalic carbaldehyde in tetrahydrofuran; toluene
T=-20 - 20°C; 2 h;
参考文献
Duan, Haifeng; Sengupta, Sujata; Petersen, Jeffrey L.; Akhmedov, Novruz G.; Shi, Xiaodong
Journal of the American Chemical Society, 2009 , vol. 131, # 34 p. 12100 - 12102
反应条件
H3[PW12O40]; sodium tetrahydroborate in methanol
参考文献
Heydari, Akbar; Khaksar, Samad; Akbari, Jafar; Esfandyari, Maryam; Pourayoubi, Mehrdad; Tajbakhsh, Mahmoud
Tetrahedron Letters, 2007 , vol. 48, # 7 p. 1135 - 1138
反应条件
potassium tert-butylate in tetrahydrofuran
T=160°C; 20 h;
参考文献
Beller, Matthias; Breindl
Chemosphere, 2001 , vol. 43, # 1 p. 21 - 26
反应条件
in hexane; ethyl acetate
参考文献
Aventis Research and Technologies GmbH and Co. KG
Patent: US6222073 B1, 2001 ;
反应条件
1: With Ti(N(CH3)2)2(C6H5CONC6H3(CH(CH3)2)2)2 in toluene
T=110°C; 24 h; Schlenk techniqueInert atmosphereSealed tube;
2: With sodium cyanoborohydride; zinc(II) chloride in methanol
T=20°C; 24 h; Inert atmosphere; regioselective reaction;
参考文献
Yim, Jacky C.-H.; Bexrud, Jason A.; Ayinla, Rashidat O.; Leitch, David C.; Schafer, Laurel L.
Journal of Organic Chemistry, 2014 , vol. 79, # 5 p. 2015 - 2028
反应条件
1: Cp2TiMe2 / toluene / 24 h / 105 °C
2: 429 mg / phenylsilane; piperidine; methanol / Cp2TiMe2 / toluene / 24 h / 105 °C
View Scheme
参考文献
Heutling, Andreas; Pohlki, Frauke; Bytschkov, Igor; Doye, Sven
Angewandte Chemie - International Edition, 2005 , vol. 44, # 19 p. 2951 - 2954
反应条件
1: Cp2TiMe2 / toluene / 24 h / 105 °C
2: 429 mg / phenylsilane; piperidine; methanol / Cp2TiMe2 / toluene / 24 h / 105 °C
View Scheme
参考文献
Heutling, Andreas; Pohlki, Frauke; Bytschkov, Igor; Doye, Sven
Angewandte Chemie - International Edition, 2005 , vol. 44, # 19 p. 2951 - 2954
反应条件
lithium aluminium tetrahydride in diethyl ether
T=0°C; 1 h;
参考文献
Kimpe, Norbert De; Verhe, Roland; Buyck, Laurent De; Schamp, Niceas
Journal of Organic Chemistry, 1980 , vol. 45, # 26 p. 5319 - 5325
反应条件
iodine; tetra-n-butylphosphonium iodide; praseodymium(III) trifluoromethanesulfonate
T=160°C; 36 h; Inert atmosphere;
参考文献
Yin, Peng; Loh, Teck-Peng
Organic Letters, 2009 , vol. 11, # 17 p. 3791 - 3793
反应条件
in anhydrous xylene
T=130°C; 24 h; Inert atmosphere;
参考文献
Santoro, Federica; Psaro, Rinaldo; Ravasio, Nicoletta; Zaccheria, Federica
RSC Advances, 2014 , vol. 4, # 6 p. 2596 - 2600
