1: sec-phenethyl alcohol With iPr2NCHEt2; (-)-Tetramisole in tetrahydrofuran T=-78°C; 0.5 h; Molecular sieveInert atmosphereResolution of racemate; 2: triphenyl-silyl chloride in tetrahydrofuran T=-78°C; Inert atmosphereResolution of racemate; optical yield given as percent eeenantioselective reaction;
Marsden; Kipping
Journal of the Chemical Society, 1908 , vol. 93, p. 206
Full Text Show Details
Polis
Chemische Berichte, 1886 , vol. 19, p. 1021
Chemische Berichte, 1885 , vol. 18, p. 1542
in tetrahydrofuran byproducts: Ph3SiSiPh3; Electrolysis; electrolysis carried out galvanostatically at 25-28°C in an atm.of dry N2, electrolyte 0.4 M LiClO4/THF; hexane added to electrolyte, ppt. filtered off, filtrate analyzed for product by GC, Bu3SnSiPh3 isolated in pure by chromy.; elem. anal.;
1: sec-phenethyl alcohol With iPr2NCHEt2; (-)-Tetramisole in tetrahydrofuran T=-78°C; 0.5 h; Molecular sieveInert atmosphereResolution of racemate; 2: triphenyl-silyl chloride in tetrahydrofuran T=-78°C; Inert atmosphereResolution of racemate; optical yield given as percent eeenantioselective reaction;
