in methanol
(N2); soln. of metal compd. in dry MeOH was added to MeOH soln. of carboxylic acid (2:1 mol) at room temp. over a period of 15 min and stirred for 1 h; solvent removed in vac.; residue suspd. in warm MeOH, filtered and dried in vac. over silicagel; stored at 0°C in total darkness; elem. anal.;
参考文献
Glowacki, A.; Huber, F.; Preut, H.
Recueil des Travaux Chimiques des Pays-Bas, 1988 , vol. 107, # 3 p. 278 - 285
in further solvent(s)
the freshly prepared Sn-compd. was directly reacted with CCl3COOH in 2,2'-dimethoxypropane under N2 and stirred for 2 h;; after removal of volatiles in vac., the residue was recrystd. from CCl4 and dried in vac.;;
参考文献
Srivastava, T N; Singh, Jaideo
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1983 , vol. 22, # 8 p. 674 - 676
in benzene
byproducts: H2O; org. acid added to soln. of Ph3SnOH in benzene, refluxed for 5 h (water removed azeotropically); filtered, filtrate evapd. in vac., recrystd. from acetone/hexane; elem. anal.;
Ng, Seik Weng; Das, V. G. Kumar; Meurs, F. van; Schagen, J. D.; Straver, L. H.
Acta Crystallographica, Section C: Crystal Structure Communications, 1989 , vol. 45, p. 570 - 572
in chloroform
byproducts: water; stirring for 15 min at 20°C; water removed with Na2SO4, the soln. evapd. in vac., addn. of petroleumether, standing by cooling, washing with petroleum ether, drying in vac.; elem. anal.;
参考文献
Hager, C.-D.; Huber, F.; Barbieri, R.; Silvestri, A.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1980 , vol. 471, p. 194 - 202
Molloy, Kieran C.; Blunden, Stephen J.; Hill, Robin
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1988 , p. 1259 - 1266
in toluene
azeotropic dehydration by refluxing stoichiometric amounts of triphenyltin hydroxide and the arylcarboxylic acid in toluene, 2 hours;; recrystallization from ether - petroleum ether; elem. anal.;;
参考文献
Molloy, K. C.; Quill, K.; Blunden, S. J.; Hill, R.
Polyhedron, 1986 , vol. 5, p. 959 - 966
Molloy, Kieran C.; Blunden, Stephen J.; Hill, Robin
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1988 , p. 1259 - 1266
