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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
76068-85-4
合成路线
（共 12 条）
76068-85-4
→
反应条件
4965-09-7
1-甲基-1,2,3,4-四氢异喹啉
反应条件
sodium bis(2-methoxyethoxy)aluminium dihydride in benzene
参考文献
Lohmann, Jean-Jacques; Seebach, Dieter; Syfrig, Max A.; Yoshifuji, Masaaki
Angewandte Chemie, 1981 , vol. 93, # 1 p. 125 - 126
76068-81-0
→
反应条件
76068-85-4
反应条件
1: N-pivaloyl-1,2,3,4-tetrahydroisoquinoline With N,N,N',N,-tetramethylethylenediamine; tert.-butyl lithium in tetrahydrofuran T=-40°C; Metallation; 2: MeX in tetrahydrofuran T=-78 - 0°C; Methylation;
参考文献
Burton; Graham; Simpkins
Synlett, 2000 , # 11 p. 1640 - 1642
848772-63-4
→
反应条件
反应条件
tri-n-butyl-tin hydride; 1,1'-azobis (cyclohexanecarbonitrile) in toluene 1 h; Heating;
参考文献
Taniguchi, Tsuyoshi; Ishita, Atsuko; Uchiyama, Masahiko; Tamura, Osamu; Muraoka, Osamu; Tanabe, Genzoh; Ishibashi, Hiroyuki
Journal of Organic Chemistry, 2005 , vol. 70, # 5 p. 1922 - 1925
848772-42-9
→
反应条件
76068-85-4
反应条件
1: 64 percent / Et3N / CH2Cl2 / 0 °C 2: 68 percent / m-chloroperbenzoic acid / CH2Cl2 / 0 °C 3: 60 percent / NaHCO3 / xylene / 25 h / Heating 4: Bu3SnH; 1,1'-azobis(cyclohexanecarbonitrile) / toluene / 1 h / Heating View Scheme
参考文献
Taniguchi, Tsuyoshi; Ishita, Atsuko; Uchiyama, Masahiko; Tamura, Osamu; Muraoka, Osamu; Tanabe, Genzoh; Ishibashi, Hiroyuki
Journal of Organic Chemistry, 2005 , vol. 70, # 5 p. 1922 - 1925
848772-40-7
→
反应条件
76068-85-4
反应条件
1.1: BH3*THF / tetrahydrofuran / 1.5 h / Heating 1.2: 82 percent / I2 / tetrahydrofuran; methanol / 20 °C 2.1: 64 percent / Et3N / CH2Cl2 / 0 °C 3.1: 68 percent / m-chloroperbenzoic acid / CH2Cl2 / 0 °C 4.1: 60 percent / NaHCO3 / xylene / 25 h / Heating 5.1: Bu3SnH; 1,1'-azobis(cyclohexanecarbonitrile) / toluene / 1 h / Heating View Scheme
参考文献
Taniguchi, Tsuyoshi; Ishita, Atsuko; Uchiyama, Masahiko; Tamura, Osamu; Muraoka, Osamu; Tanabe, Genzoh; Ishibashi, Hiroyuki
Journal of Organic Chemistry, 2005 , vol. 70, # 5 p. 1922 - 1925
848772-57-6
→
反应条件
76068-85-4
反应条件
1: 68 percent / m-chloroperbenzoic acid / CH2Cl2 / 0 °C 2: 60 percent / NaHCO3 / xylene / 25 h / Heating 3: Bu3SnH; 1,1'-azobis(cyclohexanecarbonitrile) / toluene / 1 h / Heating View Scheme
参考文献
Taniguchi, Tsuyoshi; Ishita, Atsuko; Uchiyama, Masahiko; Tamura, Osamu; Muraoka, Osamu; Tanabe, Genzoh; Ishibashi, Hiroyuki
Journal of Organic Chemistry, 2005 , vol. 70, # 5 p. 1922 - 1925
848772-83-8
→
反应条件
76068-85-4
反应条件
1: 60 percent / NaHCO3 / xylene / 25 h / Heating 2: Bu3SnH; 1,1'-azobis(cyclohexanecarbonitrile) / toluene / 1 h / Heating View Scheme
参考文献
Taniguchi, Tsuyoshi; Ishita, Atsuko; Uchiyama, Masahiko; Tamura, Osamu; Muraoka, Osamu; Tanabe, Genzoh; Ishibashi, Hiroyuki
Journal of Organic Chemistry, 2005 , vol. 70, # 5 p. 1922 - 1925
18698-97-0
邻溴苯乙酸
→
反应条件
76068-85-4
反应条件
1.1: 74 percent / 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride / CH2Cl2 / 20 °C 2.1: BH3*THF / tetrahydrofuran / 1.5 h / Heating 2.2: 82 percent / I2 / tetrahydrofuran; methanol / 20 °C 3.1: 64 percent / Et3N / CH2Cl2 / 0 °C 4.1: 68 percent / m-chloroperbenzoic acid / CH2Cl2 / 0 °C 5.1: 60 percent / NaHCO3 / xylene / 25 h / Heating 6.1: Bu3SnH; 1,1'-azobis(cyclohexanecarbonitrile) / toluene / 1 h / Heating View Scheme
参考文献
Taniguchi, Tsuyoshi; Ishita, Atsuko; Uchiyama, Masahiko; Tamura, Osamu; Muraoka, Osamu; Tanabe, Genzoh; Ishibashi, Hiroyuki
Journal of Organic Chemistry, 2005 , vol. 70, # 5 p. 1922 - 1925
3282-30-2
三甲基乙酰氯
→
反应条件
76068-85-4
反应条件
1: 90 percent / Et3N / diethyl ether / Ambient temperature 2: 1) tBuLi/TMEDA / 1) THF, -80 deg C, 5min View Scheme
参考文献
Lohmann, Jean-Jacques; Seebach, Dieter; Syfrig, Max A.; Yoshifuji, Masaaki
Angewandte Chemie, 1981 , vol. 93, # 1 p. 125 - 126
91-21-4
1,2,3,4-四氢异喹啉
→
反应条件
76068-85-4
反应条件
1: 91 percent / Et3N / diethyl ether / 24 h / Ambient temperature 2: 1) t-BuLi, TMEDA / 1) THF, isopentane, -78 deg C, 20 min; 2) -78 deg C, 15 min View Scheme
参考文献
Seebach, Dieter; Lohmann, Jean-Jacques; Syfrig, Max A.; Yoshifuji, Masaaki
Tetrahedron, 1983 , vol. 39, # 12 p. 1963 - 1974
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