R-(+)-1,1'-联萘-2,2'-双二苯膦合成路线 （共 19 条）
反应条件
zinc; nickel(II) dichloride T=110 - 120°C;
参考文献
Tetrahedron Letters, , vol. 48, # 6 p. 949 - 953
反应条件
in benzene under N2; a soln. of the ligand in benzene was added to a mixt. of the Pd-complex and benzene, stirred overnight; filtered, washed with benzene, dried under vac., dissolved in acetone, layered with hexane, stand at room temp.; elem. anal.;
参考文献
Organometallics, , vol. 12, p. 4188 - 4196
反应条件
in acetone solvent removed in vac.;
参考文献
Turova, Olga V.; Starodubtseva, Eugenia V.; Vinogradov, Maxim G.; Ferapontov, Vladimir A.
Journal of Molecular Catalysis A: Chemical, 2009 , vol. 311, # 1-2 p. 61 - 65
反应条件
in methanol; acetone Ru-complex, ligand were dissolved in acetone, HCl in MeOH was added, stirred for 1 h; solvent was removed in vacuo;
参考文献
Albert, Matthias; Seebach, Dieter; Duchardt, Elke; Schwalbe, Harald
Helvetica Chimica Acta, 2002 , vol. 85, # 2 p. 633 - 658
反应条件
in methanol; acetone Ru complex and (R)-2,2'- bis(diphenylphosphino)-1,1'-binaphthyl placed in glass tube; evacuated; filled with Ar; soln. of HCl in MeOH added to anhyd. acetone; degassed; injected to mixt. of ligand and Ru complex; mixt. stirred for 0.5 h; solvent evapd. (vac.);
参考文献
Starodubtseva; Turova; Vinogradov; Gorshkova; Ferapontov
Russian Chemical Bulletin, 2005 , vol. 54, # 10 p. 2374 - 2378
反应条件
in acetone solvent removed in vac.;
参考文献
Turova, Olga V.; Starodubtseva, Eugenia V.; Vinogradov, Maxim G.; Ferapontov, Vladimir A.
Journal of Molecular Catalysis A: Chemical, 2009 , vol. 311, # 1-2 p. 61 - 65
反应条件
in methanol; acetone Ru-complex, ligand were dissolved in acetone, HCl in MeOH was added, stirred for 1 h; solvent was removed in vacuo;
参考文献
Albert, Matthias; Seebach, Dieter; Duchardt, Elke; Schwalbe, Harald
Helvetica Chimica Acta, 2002 , vol. 85, # 2 p. 633 - 658
反应条件
in methanol; acetone Ru complex and (R)-2,2'- bis(diphenylphosphino)-1,1'-binaphthyl placed in glass tube; evacuated; filled with Ar; soln. of HCl in MeOH added to anhyd. acetone; degassed; injected to mixt. of ligand and Ru complex; mixt. stirred for 0.5 h; solvent evapd. (vac.);
参考文献
Starodubtseva; Turova; Vinogradov; Gorshkova; Ferapontov
Russian Chemical Bulletin, 2005 , vol. 54, # 10 p. 2374 - 2378
反应条件
in benzene under N2; a soln. of the ligand in benzene was added to a mixt. of the Pd-complex and benzene, stirred overnight; filtered, washed with benzene, dried under vac., dissolved in acetone, layered with hexane, stand at room temp.; elem. anal.;
参考文献
Ozawa, Fumiyuki; Kubo, Akihiko; Matsumoto, Yonetatsu; Hayashi, Tamio; Nishioka, Eriko; et al.
Organometallics, 1993 , vol. 12, p. 4188 - 4196
