dinitrogen pentaoxide in acetonitrile T=-15 - 10°C; Further byproducts given;
参考文献
Churakov, Aleksandr M.; Smirnov, Oleg Yu.; Ioffe, Sema L.; Strelenko, Yuri A.; Tartakovsky, Vladimir A.
European Journal of Organic Chemistry, 2002 , # 14 p. 2342 - 2349
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反应条件
ammonia in acetonitrile t-BuSnMe3 in CH3CN added to Fe(phen)3(ClO4)3 in CH3CN at 22°C under Ar and soln. stirred for 2 h, drop water added, Fe(II) complex filtered, filtrate dried with MgSO4 and treated with anhyd. aq. NH3, Sn product treated with HCl and sublimed;
参考文献
Journal of the American Chemical Society, , vol. 104, # 5 p. 1319 - 1330
→
反应条件
ammonia in acetonitrile byproducts: trans-2-butene, cis-2-butene; i-BuSnMe3 in CH3CN added to Fe(phen)3(PF6)3 in CH3CN at 22°C under Ar and soln. stirred for 2 h, drop water added and Fe(II) complex filtered, filtrate dried with MgSO4 and treated anhyd. NH3 and Sn product filtered;
参考文献
Rollick; Kochi
Journal of the American Chemical Society, 1982 , vol. 104, # 5 p. 1319 - 1330
