5-甲基-1,4-己二烯合成路线 （共 29 条）
反应条件
(i) 9-borabicyclo<3.3.1>nonane, (ii) aq. NaOH, H2O2; Multistep reaction;
参考文献
Marfat,A. et al.
Journal of Organic Chemistry, 1979 , vol. 44, # 22 p. 3888 - 3901
反应条件
1: 5-methyl-1,4-hexadiene With n-butyllithium; potassium tert-butylate in hexane 2: With [TiCl(isopropoxy)3] in tetrahydrofuran 3: acetone in tetrahydrofuran
参考文献
Zellner; Schlosser
Synlett, 2001 , # SPEC. ISS p. 1016 - 1018
反应条件
1: (i) 9-bora-bicyclo<3.3.1>nonane, THF, (ii) aq. NaOH, H2O2 2: pyridinium chlorochromate / CH2Cl2 / 2 h / Ambient temperature 3: diethyl ether View Scheme
参考文献
Marfat,A. et al.
Journal of Organic Chemistry, 1979 , vol. 44, # 22 p. 3888 - 3901
反应条件
1: (i) 9-bora-bicyclo<3.3.1>nonane, THF, (ii) aq. NaOH, H2O2 2: pyridinium chlorochromate / CH2Cl2 / 2 h / Ambient temperature 3: diethyl ether View Scheme
参考文献
Marfat,A. et al.
Journal of Organic Chemistry, 1979 , vol. 44, # 22 p. 3888 - 3901
反应条件
triphenylphosphine; bis(dibenzylideneacetone)-palladium(0) in chloroform
T=25°C; P=2585.7 Torr; 24 h;
参考文献
Sheffy; Godschalx; Stille
Journal of the American Chemical Society, 1984 , vol. 106, # 17 p. 4833 - 4840
反应条件
carbon monoxide; triphenylphosphine; bis(dibenzylideneacetone)-palladium(0) in chloroform
T=25°C; P=2585.7 Torr; 24 h;
参考文献
Sheffy; Godschalx; Stille
Journal of the American Chemical Society, 1984 , vol. 106, # 17 p. 4833 - 4840
反应条件
Ni(dmpe)Cl2 in diethyl ether
参考文献
The University of Akron
Patent: US5245098 A1, 1993 ;
反应条件
in methanol
8 h; Irradiation;
参考文献
Manning, T. D. R.; Kropp, Paul J.
Journal of the American Chemical Society, 1981 , vol. 103, # 4 p. 889 - 897
反应条件
triethylaluminum; phosphorus trichoride in toluene
T=40°C; 2 h;
参考文献
Tajima,Y.; Kunioka,E.
Chemical Communications (London), 1968 , p. 603
反应条件
{[2,6-(2,6-Me2C6H3N=CMe)2C5H3N]Fe(N2)}2(μ2-N2) in benzene-d6
T=23°C; 16 h; Inert atmosphere;
参考文献
Russell, Sarah K.; Lobkovsky, Emil; Chirik, Paul J.
Journal of the American Chemical Society, 2011 , vol. 133, # 23 p. 8858 - 8861
