5-甲基-1,4-己二烯合成路线 （共 29 条）
反应条件
T=350°C; P=129287 Torr;
参考文献
Cywinski,N.F.
Journal of Organic Chemistry, 1965 , vol. 30, p. 361 - 364
反应条件
1: 16 g / sodium hydroxide / H2O
2: 11.7 g / pyridine / H2O / 2 h / Heating
3: 18.4 g / lithium aluminium hydride / diethyl ether / 1.) 0 deg C, 2.) reflux, 1 h
4: 1.) toluene-p-sulphonyl chloride,pyridine, 2.) sodium iodide / 1.) 24 h, 2.) acetone, reflux, 16 h
5: 24 g
6: water, silver oxide / 15 °C
7: 150 - 160 °C
View Scheme
参考文献
Cocker, Wesley; Geraghty, Niall W. A.; McMurry, T. Brian H.; Shannon, Patrick V. R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 10 p. 2245 - 2254
反应条件
1: 18.4 g / lithium aluminium hydride / diethyl ether / 1.) 0 deg C, 2.) reflux, 1 h
2: 1.) toluene-p-sulphonyl chloride,pyridine, 2.) sodium iodide / 1.) 24 h, 2.) acetone, reflux, 16 h
3: 24 g
4: water, silver oxide / 15 °C
5: 150 - 160 °C
View Scheme
参考文献
Cocker, Wesley; Geraghty, Niall W. A.; McMurry, T. Brian H.; Shannon, Patrick V. R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 10 p. 2245 - 2254
反应条件
1: 11.7 g / pyridine / H2O / 2 h / Heating
2: 18.4 g / lithium aluminium hydride / diethyl ether / 1.) 0 deg C, 2.) reflux, 1 h
3: 1.) toluene-p-sulphonyl chloride,pyridine, 2.) sodium iodide / 1.) 24 h, 2.) acetone, reflux, 16 h
4: 24 g
5: water, silver oxide / 15 °C
6: 150 - 160 °C
View Scheme
参考文献
Cocker, Wesley; Geraghty, Niall W. A.; McMurry, T. Brian H.; Shannon, Patrick V. R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 10 p. 2245 - 2254
反应条件
1: 40 g / ethanol / 1.) 15 deg C, 6 h, 2.) reflux, 0.5 h
2: 16 g / sodium hydroxide / H2O
3: 11.7 g / pyridine / H2O / 2 h / Heating
4: 18.4 g / lithium aluminium hydride / diethyl ether / 1.) 0 deg C, 2.) reflux, 1 h
5: 1.) toluene-p-sulphonyl chloride,pyridine, 2.) sodium iodide / 1.) 24 h, 2.) acetone, reflux, 16 h
6: 24 g
7: water, silver oxide / 15 °C
8: 150 - 160 °C
View Scheme
参考文献
Cocker, Wesley; Geraghty, Niall W. A.; McMurry, T. Brian H.; Shannon, Patrick V. R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 10 p. 2245 - 2254
反应条件
T=350°C; P=129287 Torr;
参考文献
Cywinski,N.F.
Journal of Organic Chemistry, 1965 , vol. 30, p. 361 - 364
参考文献
Meinwald,J.; Smith,G.W.
Journal of the American Chemical Society, 1967 , vol. 89, p. 4923 - 4932
反应条件
1: 1.) toluene-p-sulphonyl chloride,pyridine, 2.) sodium iodide / 1.) 24 h, 2.) acetone, reflux, 16 h
2: 24 g
3: water, silver oxide / 15 °C
4: 150 - 160 °C
View Scheme
参考文献
Cocker, Wesley; Geraghty, Niall W. A.; McMurry, T. Brian H.; Shannon, Patrick V. R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 10 p. 2245 - 2254
反应条件
1: 24 g
2: water, silver oxide / 15 °C
3: 150 - 160 °C
View Scheme
参考文献
Cocker, Wesley; Geraghty, Niall W. A.; McMurry, T. Brian H.; Shannon, Patrick V. R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 10 p. 2245 - 2254
反应条件
1: water, silver oxide / 15 °C
2: 150 - 160 °C
View Scheme
参考文献
Cocker, Wesley; Geraghty, Niall W. A.; McMurry, T. Brian H.; Shannon, Patrick V. R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 10 p. 2245 - 2254
