5-甲基-1,4-己二烯合成路线 （共 29 条）
反应条件
lithium
1) ether, THF, -60 deg C, 2) -60 deg C, 8 h; Yield given. Multistep reaction;
参考文献
Barluenga, Jose; Yus, Miguel; Concellon, Jose M.; Bernad, Pablo
Journal of Chemical Research, Miniprint, 1980 , # 2 p. 677 - 692
反应条件
T=150 - 160°C; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Cocker, Wesley; Geraghty, Niall W. A.; McMurry, T. Brian H.; Shannon, Patrick V. R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 10 p. 2245 - 2254
反应条件
(i) CuBr*Me2S, Et2O, Me2S, (ii) /BRN= 878138/, (iii) /BRN= 605308/, HMPT; Multistep reaction;
参考文献
Marfat,A. et al.
Journal of Organic Chemistry, 1979 , vol. 44, # 22 p. 3888 - 3901
反应条件
T=150 - 160°C; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Cocker, Wesley; Geraghty, Niall W. A.; McMurry, T. Brian H.; Shannon, Patrick V. R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 10 p. 2245 - 2254
反应条件
T=150 - 160°C; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Cocker, Wesley; Geraghty, Niall W. A.; McMurry, T. Brian H.; Shannon, Patrick V. R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 10 p. 2245 - 2254
反应条件
T=150°C; P=50 Torr; 6 h; Irradiationvarious temp. and pressure; Quantum yieldMechanism;
参考文献
Mariano, Patrick S.; Bay, Elliott; Watson, Darrell G.; Rose, Timothy; Bracken, Christopher
Journal of Organic Chemistry, 1980 , vol. 45, # 10 p. 1753 - 1762
反应条件
Dehydratisieren nach der Xanthogenatmethode;
参考文献
Karassew; Chabarowa
Zhurnal Obshchei Khimii, 1940 , vol. 10, p. 1645
Chem. Zentralbl., 1942 , vol. 113, # I p. 28
反应条件
1: (i) 9-bora-bicyclo<3.3.1>nonane, THF, (ii) aq. NaOH, H2O2
2: pyridinium chlorochromate / CH2Cl2 / 2 h / Ambient temperature
View Scheme
参考文献
Marfat,A. et al.
Journal of Organic Chemistry, 1979 , vol. 44, # 22 p. 3888 - 3901
参考文献
Meinwald,J.; Smith,G.W.
Journal of the American Chemical Society, 1967 , vol. 89, p. 4923 - 4932
