反应条件
Mg; aq. HCl in diethyl ether; toluene under Ar, Mg was heated to 100 °C without solvent, ClCH2SiMe3 wasadded in ether at room temp., mixt. was cooled to 0 °C, stirred for 1 h, SnCl4 was added in toluene, mixt. was kept at 0 °C, refl ux for 8 h; mixt. was cooled in ice-bath, hydrolysed with 5 percent aq. HCl, layers were sepd., aq. layer was extd. 3 times with Et2O, combined org. phase was dried over Na2SO4, solvent was removed in vac., liquid was distd. at 35 °C/10 Hgmm, elem. anal.;
参考文献
Aziz Choudhary; Mazhar; Salma; Ali; Qinglan; Molloy
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 2001 , vol. 31, # 2 p. 277 - 295
