cis-Pt(Cl)2(PPh3)2 in toluene stirred for 2 h at 110°C, catalyst added stirred for 12 h at 110°C; cooled to room temp., filtered, ppt. (SnCl2) washed (toluene), dried, filtrate evapd. (vac.), distilled (90°C/11 mm Hg);
Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.5.4.5, page 106 - 108
Full Text Show Details
Carlisle Chemical Works, Inc.
Patent: NL6513659 , 1966 ;
C.A., 1966 , vol. 65, p. 7218
Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.5.4.5, page 106 - 108
Full Text Show Details
Noltes, J. G.; Kerk, G. J. M. van der
Functionally Substituted Organotin Compounds, Tin Research Institute, Greenford 1958, S. 1/128
in neat (no solvent) slow heating of a mixt. of Sn-compd. and SnCl4 at 190°C for 2 h under N2, further heating at 205°C for 40 min; dissolution of resulting oil in hexane, removing slight turbidity by filtn., cooling to -78°C, filtn., rapidly washing with cold hexane, evapn. of mother liquor yields second crop, elem. anal.;
参考文献
Schenk, Wolfdieter A.; Khadra, Almuetassem; Burschka, Christian
Journal of Organometallic Chemistry, 1994 , vol. 468, # 1-2 p. 75 - 86
n-butyllithium in diethyl ether; benzene boiling, 12h;;
参考文献
Ursino, J. A.
Diss. Abstr. B, Diss. St. John's Univ. 1967, 99 S. 1968 , vol. 28, p. 3662
Full Text Show Details
Kupchik, E. J.; Ursino, J. A.; Boudjouk, P. R.
Journal of Organometallic Chemistry, 1967 , vol. 10, p. 269 - 278
