in toluene
(N2); SnCl4 soln. added dropwise at -40°C to Sn complex soln. at1/4 molar ratio, warmed to room temp., stirred overnight, heated for 2 h at 80°C; evapd., hexane added, powder collected, dried (vac.); elem. anal.;
参考文献
Bonomo, Lucia; Solari, Euro; Scopelliti, Rosario; Floriani, Carlo; Re, Nazzareno
Journal of the American Chemical Society, 2000 , vol. 122, # 22 p. 5312 - 5326
AlCl3 in neat (no solvent)
byproducts: CH3SiCl3; heated for 1 h to 125°C; stirred for 2 h; heated to 135-140°C and then at 145-150°C for 2 h; AlCl3 sepd.; vacuum-distd.; elem. anal.;
参考文献
Motsarev, G. V.; Chernyshev, E. A.; Rozenberg, V. R.; Inshakova, V. T.; Zetkin, V. I.
Journal of General Chemistry USSR (English Translation), 1983 , vol. 53, p. 985 - 988
Zhurnal Obshchei Khimii, 1988 , vol. 53, p. 1111 - 1114
