slow addn. of a moderately concd. soln. of KCN to a soln. of ZnCl until the end of pptn.;; washing of the pptn. with water; drying with alc. and diethyl ether;;
in neat (no solvent) Electrolysis; crumbling of V-anode;; leakage of VCl4;;
参考文献
Marino, L.
Gazzetta Chimica Italiana, 1904 , vol. 34, # I p. 230 - 247
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Marino, L.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1904 , vol. 39, p. 152 - 169
in anhydrous butyl ether soln. MeMgI in n-Bu2O was slowly added to ZnCl2 under vigorous stirring,suspn. was heated at 60°C for 60 h; ZnMe2 was collected by distillation in temp. range 130-160°C;
参考文献
Lizandara-Pueyo; Van Den Berg; De Toni; Goes; Polarz
Journal of the American Chemical Society, 2008 , vol. 130, # 49 p. 16601 - 16610
