in neat (no solvent, solid phase) byproducts: NaCl; placing of ZnCl2 and NaS2CNEt2 in 1:2 ratio to the reactor; sealing, vibrating for 10 min; sublimating at 150-165°C in vac.; crystn.; elem. anal.;
参考文献
Petrova; Makhaev
Russian Journal of Inorganic Chemistry, 2007 , vol. 52, # 6 p. 865 - 870
2,6-dimethylpyridine in tetrahydrofuran Ar atmosphere; stirring (40°C, 30 min); solvent evapn., dissolving (toluene), silica-gel column, washing (toluene, then CH2Cl2/acetone = 50/1 v/v), recrystn. (MeOH/H2O); elem. anal.;
参考文献
Tsukahara, Keiichi; Sawai, Naoko; Hamada, Satoko; Nakazawa, Takashi; Nakagaki, Ryoichi
Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 7 p. 1947 - 1954
in neat (no solvent, solid phase) mechanically activated solid state synthesis; eccentric-type ball mill, mixt. was treated for 30 min; mixt. was sepd. by vacuum sublimation on an oil bath at 120-160°Cand pressure of 13.3 Pa; elem. anal., XRD;
参考文献
Russian Journal of Inorganic Chemistry, , vol. 47, # 12 p. 1827 - 1832
1: para-bromotoluene With n-butyllithium in tetrahydrofuran T=-78°C; 1 h; Sealed tubeInert atmosphere; 2: zinc(II) chloride in tetrahydrofuran T=-78 - 20°C; Sealed tubeInert atmosphere;
参考文献
Dennis, Joseph M.; Calyore, Catherine M.; Sjoholm, Jessica S.; Lutz, J. Patrick; Gair, Joseph J.; Johnson, Jeffrey B.
Synlett, 2013 , vol. 24, # 19 art. no. ST-2013-S0592-L, p. 2567 - 2570
