in tetrahydrofuran T=20°C; 1 h; Schlenk technique;
参考文献
Bedford, Robin B.; Carter, Emma; Cogswell, Paul M.; Gower, Nicholas J.; Haddow, Mairi F.; Harvey, Jeremy N.; Murphy, Damien M.; Neeve, Emily C.; Nunn, Joshua
Angewandte Chemie - International Edition, 2013 , vol. 52, # 4 p. 1285 - 1288
in ethanol; water stoich. amt. of aq. soln. of ZnCl2 added to alcoholic soln. of org. compd.; ppt. filtered and washed with EtOH and water, characterized by powder XRD patterns;
参考文献
Barman; Vasudevan
Journal of Physical Chemistry B, 2006 , vol. 110, # 45 p. 22407 - 22414
magnesium in toluene under N2, Cl-compd. was added to Et2O suspn. of the activated Mg, stirring for 2 h, soln. was filtered and anhyd. ZnCl2 was added, stirring overnight; soln. was filtered, volatiles were removed in vac.;
参考文献
Green, Malcolm L.H.; Conway, Stephen L.J.; Doerrer, Linda H.
Polyhedron, 2005 , vol. 24, # 11 p. 1388 - 1403
in diethyl ether; pentane byproducts: LiCl; (Ar); std. Schlenk technique; soln. of BuLi in pentane was added over 1 h to soln. of ZnCl2 in Et2O at 0°C; slowly warmed to room temp.; stirred for 1 h; filtered through Celite; solvent removed (vac.); sublimed under partial vac. at room temp.;
参考文献
Sarazin, Yann; Wright, Joseph A.; Harding, Duncan A.J.; Martin, Eddy; Woodman, Timothy J.; Hughes, David L.; Bochmann, Manfred
Journal of Organometallic Chemistry, 2008 , vol. 693, # 8-9 p. 1494 - 1501
