in water formation of SbOCl and HCl by hydrolysis of SbCl3; react. of SbOCl with HCl and Na2S2O3 forming Na3Sb(S2O3), NaCl and H2O;; formation of a soln. of Na3Sb(S2O3), not isolated; pptn. with alcohol at -12 °C impossible; decomposition on evaporating;;
hydrogenchloride; nickel dichloride in water gradual addn. of solid (15)N-enriched NaNO2 to soln. of RuCl3 in 3.5 M HCl in the presence of NiCl2, heating after gas evolution ceased on water bath for approx. 1.5 h; filtration, washing solids with water; X-ray diffraction, NMR;
参考文献
Russian Journal of Inorganic Chemistry, , vol. 45, # 5 p. 728 - 733
in diethyl ether addn. of hemiquinolate in ether to soln. of (i-Pr)3GeCl in Et2O; removal of ether, addn. of hexane, sepn. of NaCl (filtration off), evapn., crystn. (low temp.);
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 31, p. 1888 - 1893
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 9 p. 2138 - 2144
