in neat (no solvent) 1200°C;; simultaneous preparation of Na and Mg;;
参考文献
Gmelin Handbook: Na: SVol.1, 4, page 10 - 16
Full Text Show Details
Nikolajshvili, N. M.
C. A., Sborn. nauchno-techn. Inform. Nr. 1 (1955) 148/9 1958 , p. 3620
evapn. of reaction mixture formed from BaN6 and alkali chloride to dryness, then reaction at temp. of distn. of product; alkali metal distilles off; incomplete reaction for Na;
O; copper(II) oxide in neat (no solvent) byproducts: Cl2; calcination of Fe2S with NaCl, O at 450-500 °C; molar ratio of educts 2:8:16 (Fe2S:NaCl:O); catalyst CuO;;
参考文献
Krutwig; Dernoncourt
Rec. Trav. chim., 1898 , vol. 17, p. 349 - 349
Full Text Show Details
Krutwig
Rec. Trav. chim., 1897 , vol. 16, p. 173 - 173
Full Text Show Details
Gmelin Handbook: Na: MVol., 177, page 537 - 538
iron(III) oxide equivalent amt. NaCl and Fe2O3; below 1350°C;
参考文献
Gmelin Handbook: Na: SVol.6, 6.2.5.8, page 395 - 396
Full Text Show Details
Shumilin, A. M.
C.A., Sb. Nauch. Tr. Beloruss. Politekh. Inst. Nr. 86 (1960) 12/5 1961 , p. 18041
in neat (no solvent) on the surface of ionic crystal NaCl; at temp. gradient (or without temp. gradient); external potential applied (or without external potential);
参考文献
Solunskii, B. I.
Doklady Physical Chemistry (Translation of the physical chemistry section of Doklady Akademii Nauk), 1981 , vol. 257, p. 188 - 190
Doklady Akademii Nauk SSSR, 1981 , vol. 257, p. 160 - 162
→
反应条件
byproducts: Na2SO4, SO2; information about the react. eqs. in detail; react. with NaCl between 285 and 290°C, oxidn. of FeCl2 to FeCl3 at 350°C in presence of O2;
