in water
byproducts: H, Ca(OH)2; Electrolysis; electrolysis without diaphragm, cathode reaction; additive CaCl2; formation of acidic soln. and therefore formation of ClO3 because of pptn. of Ca(OH)2;;
in neat (no solvent)
heating with CaF2 in presence of NaCl;;
参考文献
Tarbutton, G.; Egan, E. P.; Frary, S. G.
Journal of the American Chemical Society, 1941 , vol. 63, p. 1782 - 1789
→
反应条件
in neat (no solvent)
byproducts: POF3, POCl3, HCl; heating P2O5, NaCl and CaF2 at 350-400 °C; ratio of products depending on mixing ratio of educts;; isolation from PF3, POF3, POCl3 and HCl by fractional distn.;;
参考文献
Gmelin Handbook: P: MVol.C, 212, page 487 - 489
→
反应条件
T=120 - 145°C; SolventTemperature;
参考文献
Chemtura Corporation; Maggiarosa, Nicola; Preetz, Angelika; Sikora, David J.
Patent: US2013/197252 A1, 2013 ;
Location in patent: Paragraph 0060 ;
in water
Electrolysis; at pH = 8; > 8.1 g/l NaCl;;
参考文献
Narasimham, K. C.; Sundararajan, S.; Udupa, H. V. K.
Journal of the Electrochemical Society, 1961 , vol. 108, p. 798 - 805
Full Text Show Details
Gmelin Handbook: Cl: SVol.A, 144, page 330 - 333
Pamfilov, A. V.; Fedorova, O. S.
Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1928 , vol. 60, p. 765 - 770
Full Text Show Details
Gmelin Handbook: Cl: SVol.A, 142, page 325 - 328
Izgarishev, N. A.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1950 , p. 15 - 26
C., 1951 , vol. II, p. 642
Full Text Show Details
Gmelin Handbook: Cl: SVol.A, 142, page 325 - 328
