反应条件
nitric acid in neat (no solvent)
two-times distilled PCl3 is slowly mixed with H2O in flat, cooled porcelain crucible, formed H3PO3 is heating as long there is precipitate with AgNO3, subsequent oxidation with HNO3;; excess HNO3 is removed via heating;;
参考文献
Phillips, H. E. W.
Journal of the Chemical Society, 1909 , vol. 95, p. 59 - 66
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Phillips, H. E. W.
Proceedings of the Chemical Society, London, 1908 , vol. 24, p. 239 - 240