sulfuric acid; nitric acid in sulfuric acid; nitric acid
byproducts: nitrogen oxide; phosphorus dissolves even at 0 °C in a mixt. of HNO3:H2SO4 = 1:9 without evolution of gas; addn. of H2O to the soln. causes release of nitrous oxides and formation of H3PO4 and some H3PO3;; small amount of phosphorous acid;;
参考文献
Schoenbein, C. F.
Annalen der Physik (Weinheim, Germany), 1847 , vol. 70, p. 87 - 99
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Gmelin Handbook: S: MVol.B3, 72, page 1691 - 1693
sulfuric acid in neat (no solvent)
byproducts: nitrous oxides; inflammation on contact with a mixture of fuming HNO3 and concd. H2SO4; evolution of red vapours;;
参考文献
Dietzenbacher
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1865 , vol. 60, p. 1022 - 1023
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Gmelin Handbook: S: MVol.B3, 72, page 1691 - 1693
Smith, E. F.; Meyer, F. L.
Journal of the American Chemical Society, 1895 , vol. 17, p. 737
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Gmelin Handbook: Br: MVol., 6.3, page 208 - 213
in water
byproducts: HI; oxidation of H3PO3 with HIO3 at ambient temp. after 16 h;;
参考文献
Hovorka, V.
Collection of Czechoslovak Chemical Communications, 1930 , vol. 2, p. 559 - 570
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Gmelin Handbook: P: MVol.C, 62, page 132 - 134
